Answer:
0.031 m
HgO(s) ⇒ Hg(l) + 1/2 O₂(g)
Chemical change
Element
Explanation:
A 75 gram solid cube of mercury (II) oxide has a density of 2.4 × 10³ kg/m³. What is the length of one side of the cube in cm?
Step 1: Convert the mass to kilograms
We will use the relationship 1 kg = 1,000 g.
[tex]75g \times \frac{1kg}{1,000g} = 0.075kg[/tex]
Step 2: Calculate the volume (V) of the cube
[tex]0.075kg \times \frac{1m^{3} }{2.4 \times 10^{3} kg} = 3.1 \times 10^{-5} m^{3}[/tex]
Step 3: Calculate the length (l) of one side of the cube
We will use the following expression.
[tex]V = l^{3} \\l = \sqrt[3]{V} = \sqrt[3]{3.1 \times 10^{-5} m^{3} }=0.031m[/tex]
The mercury (II) oxide completely dissociates and forms liquid mercury and oxygen gas. Write a balanced chemical equation and indicate if this process is a chemical or physical change?
The balanced chemical equation is:
HgO(s) ⇒ Hg(l) + 1/2 O₂(g)
This is a chemical change because new substances are formed.
The oxygen gas escapes and now you are left with liquid grey substance. Is this grey substance a compound, element, homogeneous mixture or heterogeneous mixture?
The liquid gray substance is Hg(l), which is an element because it is formed by just one kind of atoms.
How do the particles in plasmas compare with the particles in solids?
Answer:
Plasmas and solids are both made up of cation-anion pairs. Solids and plasmas are both made up of electrons and cations. Solids are made up of cation-anion pairs, but plasmas are not.
Answer:
Solids are made up of cation-anion pairs, but plasmas are not.
Explanation:
How many grams of the salt CaF2 (g) are formed when 15.7 mL of 0.612 M KF reacts with an excess of aqueous calcium bicarbonate (Ca(HCO3)2) via a metathesis reaction?
Answer:
[tex]m_{CaF_2}0.375gCaF_2[/tex]
Explanation:
Hello,
In this case, for the studied reaction:
[tex]2KF+Ca(HCO_3)_2\rightarrow CaF_2+2KHCO_3[/tex]
Thus, the first step is to compute the reacting moles of potassium fluoride by using its volume and molarity:
[tex]n_{KF}=0.0157L*0.612\frac{mol}{L} =9.61x10^{-3}molKF[/tex]
Then, we apply the 2:1 molar ratio between potassium fluoride and calcium fluoride to compute the produced moles of calcium fluoride:
[tex]n_{CaF_2}=9.61x10^{-3}molKF*\frac{1molCaF_2}{2molKF} =4.80x10^{-3}molCaF_2[/tex]
Finally, by using the molar mass of calcium fluoride (78.07 g/mol) we can compute its produced grams:
[tex]m_{CaF_2}=4.80x10^{-3}molCaF_2*\frac{78.07gCaF_2}{1molCaF_2} \\\\m_{CaF_2}0.375gCaF_2[/tex]
Best regards.
3. Crystalline structural unit of barium metal is a body-centered cubic cell. The edge length of the unit cell is 5.02x10-8 cm. The density of the metal is 5.30 g/cm3. Assume that 68% of the unit cell is occupied by Ba atoms. The molar mass of barium is 137.3 g/mol. Using this information, calculate Avogadro’s number. Show your calculation procedure that allows you to derive Avogadro’s number. Your answer must show six digits after the decimal point (i.e., 6.pppx1023) that is not necessarily the same as the known value. By showing your calculation-result down to six digits after the decimal point, you showcase that you did calculate the number, instead of simply adopting the known Avogadro’s number available in open resources.
Answer:
The Avogadro's number is [tex]N_A = 6.02289 *10^{23}[/tex]
Explanation:
From the question we are told that
The edge length is [tex]L = 5.02 * 10^{-8} \ cm= \frac{5.02 * 10^{-8} }{100} = 5.02 * 10^{-10}[/tex]
The density of the metal is [tex]\rho = 5.30\ g/cm^3 = 5.30 * \frac{g}{cm^3} * \frac{1*10^6}{1*10^3} = 5.30 *10^3kg/m^3[/tex]
The molar mass of Ba is [tex]Z = 137.3 \ g/mol = \frac{137.3}{1000} = 0.1373 \ kg / mol[/tex]
Generally the volume of a unit cell is
[tex]V = L^3[/tex]
substituting value
[tex]V = [5.02 *10^{-10}]^3[/tex]
[tex]V = 1.265*10^{-28}\ m^3[/tex]
From the question we are told that 68% of the unit cell is occupied by Ba atoms and that the structure is a metal which implies that the crystalline structure will be (BCC),
The volume of barium atom is
[tex]V_a = \frac{V}{2} * 0.68[/tex]
substituting value
[tex]V_a = \frac{ 1.265*10^{-28}}{2} * 0.68[/tex]
[tex]V_a = 4.301 *10^{-29} \ m^3[/tex]
The Molar mass of barium is mathematically represented as
[tex]Z = N_A V_a * \rho[/tex]
Where [tex]N_A[/tex] is the Avogadro's number
So
[tex]N_A = \frac{ Z}{ V_a * \rho}[/tex]
substituting value
[tex]N_A = \frac{ 0.1373}{ 4.301*10^{-29} * 5.3*10^{3}}[/tex]
[tex]N_A = 6.02289 *10^{23}[/tex]
Given the density of iron (Fe) is 7.87 g/cm3, determine the mass of iron (in grams) in a rectangle block with the dimensions of 12.5 in long, 3.50 in wide, and 2.50 in high. (1in = 2.54 cm).
Answer:
[tex]m=14,105.71 g Fe[/tex]
Explanation:
Hello,
In this case, the first step is to compute the volume of the block considering the length, height and width:
[tex]V=L \times W \times H =12.5 in\times 3.50 in \times 2.50 in =109.375 in^3[/tex]
Then, we compute the volume in cubic centimetres:
[tex]V=109.375in^3\times \frac{16.3871 cm^3}{1in^3} =1792.34cm^3[/tex]
Finally, as the density is given by:
[tex]\rho =\frac{m}{V}[/tex]
We solve for the mass:
[tex]m=\rho \times V= 7.87\frac{g}{cm^3} \times 1792.34 cm^3\\\\m=14,105.71 g Fe[/tex]
Best regards.
Hcl and 1-isopropylcyclohexane formation
Answer:
Spahgetti
Explanation:
How has human action affected the
population?
Answer:
Human action has affected the population in quite a negative way. Technological innovations and urbanization gave rise to a high degree of pollution on the land, air and water.
Emission of hydrocarbons from automobiles and factories are known to pollute and cause sicknesses related to the respiratory system thereby shortening the lifespan of humans. Pollution of water bodies also cause death of sea animals and thereby reducing food availability of humans.
Which of the following reactions would be predicted by the activity series list
A. A metal ion reacts with another ion to form a precipitate.
B. A metal replaces a metallic ion below it on the list.
C. A metal replaces a metallic ion above it on the list.
D. A metal reacts with oxygen in a combustion reaction.
Answer:
The answer is B) A metal replaces a metallic ion below it on the list.
Explanation:
I just did it and got it correct, luckily I didn't use the other answer posted for this question.
A metal replaces a metallic ion below it on the list give reaction which would be predicted by the activity series list.
So, option B is correct one.
What is Electrochemical series?The list in which elements arranged in the increasing order of their electrode potential values is called Electrochemical series.
The Electrochemical series is also called activity series.
To learn more about Electrochemical series here.
https://brainly.com/question/14652325
#SPJ3
Two hypothetical ionic compounds are discovered with the chemical formulas XCl2 and YCl2, where X and Y represent symbols of the imaginary elements. Chemical analysis of the two compounds reveals that 0.25 mol XCl2 has a mass of 100.0 g and 0.50 mol YCl2 has a mass of 125.0 g. (a) What are the molar masses of XCl2 and YCl2
Answer:
THE MOLAR MASS OF XCL2 IS 400 g/mol
THE MOLAR MASS OF YCL2 IS 250 g/mol.
Explanation:
We calculate the molar mass of XCL2 and YCL2 by bringing to mind the formula for molar mass when mass and amount or number of moles of the substance is given.
Number of moles = mass / molar mass
Molar mass = mass / number of moles.
For XCL2,
mass = 100 g
number of mole = 0.25 mol
So therefore, molar mass = mass / number of moles
Molar mass = 100 g / 0.25 mol
Molar mass = 400 g/mol.
For YCL2,
mass = 125 g
number of mole = 0.50 mol
Molar mass = 125 g / 0.50 mol
Molar mass = 250 g/mol.
So therefore, the molar mass of XCL2 and YCL2 IS 400 g/mol and 250 g/mol respectively.
Determine the limiting reactant in a mixture containing 95.7 g of B2O3, 75.7 g of C, and 369 g of Cl2. Calculate the maximum mass (in grams) of boron trichloride, BCl3, that can be produced in the reaction. The limiting reactant is:
Answer:
[tex]B_2O_3[/tex]
Explanation:
First, we have to find the reaction:
[tex]B_2O_3~+~C~+~Cl_2~->~BCl_3~+~CO[/tex]
The next step is to balance the reaction:
[tex]B_2O_3~+~3C~+~3Cl_2~->~2BCl_3~+~3CO[/tex]
Now, we have to calculate the molar mass for each compound, so:
[tex]B_2O_3=~69.62~g/mol[/tex]
[tex]C=~12~g/mol[/tex]
[tex]Cl_2=~70.96~g/mol[/tex]
With these values, we can calculate the moles of each compound:
[tex]95.7~g~B_2O_3\frac{1~mol~B_2O_3}{69.62~g~B_2O_3}=1.37~mol~B_2O_3[/tex]
[tex]75.7~g~C\frac{1~mol~C}{112~g~C}=6.30~mol~C[/tex]
[tex]369~g~Cl_2\frac{1~mol~Cl_2}{70.96~g~C}=5.20~mol~Cl_2[/tex]
Now we can divide by the coefficient of each compound in the balanced equation:
[tex]\frac{1.37~mol~B_2O_3}{1}=~1.37[/tex]
[tex]\frac{6.30~mol~C}{3}=~2.1[/tex]
[tex]\frac{5.20~mol~Cl_2}{3}=~1.73[/tex]
The smallest values are for [tex]B_2O_3[/tex], so this is our limiting reagent.
I hope it heps!
Which of the following best describe an atomic number? An element identity is defined by its atomic number this means it represents the number of
a)Atomic number is the number of protons in the nucleus of an atom.
b)atomic number represents the number of protons
An element's identity is defined by its atomic number; this means it represents the number of protons in its nucleus.
The question is incomplete, the complete question is;
Which of the following best describes an atomic number? An element's identity is defined by its atomic number; this means it represents the number of
A) protons plus neutrons in its nucleus.
B) electrons in the element.
C) protons in its nucleus.
D) neutrons in its nucleus.
The subatomic particles in the atom are;
ElectronsProtonsNeutronsNeutrons and protons are contained in the nucleus hence they are collectively called nucleons.
Electrons are found in the orbits. The number of protons must be equal to the number of electrons for the atom to be electrically neutral.
The number of protons in an atom or atomic number serve as a means of identifying an atom.
Learn more; https://brainly.com/question/18460120
Empirical formula for compound of 2.17 mol N and 4.35 mol O
Answer:
Explanation:
ratio of moles of N and O in molecule =
N / O = 2.17 / 4.35
1/2
empirical formula = NO₂
Which of the following formulas represents an ionic compound?
1.HI 2.HCI 3.LiCI 4.SO2
Answer:
Numbers 4,3
Explanation:
Ionic bond is between nonmental and metals
Wine goes bad soon after opening because the ethanol dissolved in it reacts with oxygen gas to form water and aqueous acetic acid , the main ingredient in vinegar. Calculate the moles of water produced by the reaction of of oxygen. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.
Answer:
1.7 moles of ethanol would be needed.
Explanation:
* Calculate the moles of ethanol needed to produce 1.70mol of water. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.
First off, we have to state the equation for the reaction.
So we know that;
ethanol + oxygen → acetic acid + water
This leads us to;
C2H5OH + O2 → CH3COOH + H2O
1 1 1 1
To obtain the moles of ethanol needed to produce 1.70mol of water, we look at the stoichiometry of the reaction above.
1 mol of ethanol produces 1 mole of water
x mol of thanol would produce 1.7 mol of water
Thus we have;
1 = 1
x = 1.7
x = 1.7 moles of ethanol would be needed.
A 33.0−g sample of an alloy at 93.00°C is placed into 50.0 g of water at 22.00°C in an insulated coffee-cup calorimeter with a heat capacity of 9.20 J/K. If the final temperature of the system is 31.10°C, what is the specific heat capacity of the alloy? J g·°C
Answer:
THE SPECIFIC HEAT OF THE ALLOY IS 0.9765 J/g K
Explanation:
Mass of alloy = 33 g
Initial temperature of alloy = 93°C
Mass of water = 50 g
Initail temp. of water = 22 °C
Heat capacity of calorimeter = 9.20 J/K
Final temp. = 31.10 °C
specific heat of alloy = unknown
specific heat capacity of water = 4.2 J/g K
Heat = mass * specific heat * change in temperature = m c ΔT
Heat = heat capcity * chage in temperature = Δ H * ΔT
In calorimetry;
Heat lost by the alloy = Heat gained by water + Heat of the calorimeter
mc ΔT = mcΔT + Heat capacity * ΔT
33 * C * ( 93 - 31.10) = 50 * 4.2 * ( 31.10 -22) + 9.20 * ( 31.10 -22)
33 * C * 61.9 = 50 * 4.2 * 9.1 + 9.20 * 9.1
2042.7 C = 1911 + 83,72
C = 1911 + 83.72 / 2042.7
C = 1994.72 /2042.7
C =0.9765 J/g K
The specific heat of the alloy is 0.9765 J/ g K
The pyruvate dehydrogenase complex is subject to allosteric control, especially inhibition by reaction products. The main regulatory process controlling pyruvate dehydrogenase's activity in eukaryotes is
a. exchange of ADP and ATP on the pyruvate dehydrogenase complex.
b. phosphorylation by ATP, which turns the complex on, and dephosphorylation, which turns the complex off.
c. AMP binding to and activating the enzyme.
d. phosphorylation by ATP, which turns the complex off, and dephosphorylation, which turns the
Answer:
D. Phosphorylation by ATP, which turns the complex off, and dephosphorylation, which turns the complex on.
Explanation:
The pyruvate dehydrogenase complex (PDH) is responsible for the conversion of pyruvate to acetylCoA, the fuel for the citric acid cycle.
The regulation of the activity of PDH is allosterically by the products of the reaction which it catalyses. These products are ATP, acetylCoA and NADH. When their is sufficient fuel available for the needs of the cells in the form of ATP, the complex is turned off by phosphorylation of one of the two subunits of E1 (pyruvate dehydrogenase). This phosphorylation inactivates E1. When the concentration of ATP declines, a specific phosphatase removes the phosphoryl group from E1, thereby activating the complex again.
A sample of chloroform, CHCl 3 , , was determined to have a molecular mass of 112.3g / (mol) . Its molecular mass is known to be 119.5g / (mol) . Calculate the absolute error and the percent error
Answer:
Explanation:
in your case ,
Meaured value = 112.3
actual value = 119.5
Absolute error= measured value - actual value
Percent error = [measured value - actual value / actual value ] x 100
Hope this help you to find the answer
consider an exceptionally weak acid, HA, with Ka= 1 x 10-20. you make 0.1M solution of the salt NA. what is the pH.
Answer:
[tex]pH=10.5[/tex]
Explanation:
Hello,
In this case, the dissociation of the given weak acid is:
[tex]HA\rightleftharpoons H^++A^-[/tex]
Therefore, the law of mass action for it turns out:
[tex]Ka=\frac{[H^+][A^-]}{[HA]}[/tex]
That in terms of the change [tex]x[/tex] due to the reaction extent is:
[tex]1x10^{-23}=\frac{x*x}{0.1-x}[/tex]
Thus, by solving with the quadratic equation or solver, we obtain:
[tex]x=31.6x10^{-12}M[/tex]
Which clearly matches with the hydrogen concentration in the solution, therefore, the pH is:
[tex]pH=-log(-31.6x10^{-12})\\pH=10.5[/tex]
Regards.
uses of sodium chloride in daily life
Answer:
sodium chloride can be used as salt
extraction sodium metal by electrolysis
a common chemical in laboratory experiments
Answer:
sodium chloride can be used as preservatives,
in preserving foods.
A chemistry student is given 600. mL of a clear aqueous solution at 37° C. He is told an unknown amount of a certain compound X is dissolved in the solution. The student allows the solution to cool to 21° C. At that point, the student sees that a precipitate has formed. He pours off the remaining liquid solution, throws away the precipitate, and evaporates the water from the remaining liquid solution under vacuum. More precipitate forms. The student washes, dries and weighs the additional precipitate. It weighs 0.084 kg. Using only the information from above, can you calculate the solubility of X at 21° C?If yes, calculate it. Be sure your answer has a unit symbol and the right number of significant figures.
Answer:
The solubility is [tex]S = 0.0014 \ g[/tex]
Explanation:
From the question we are told that
The volume of the solution is [tex]V = 600 mL[/tex]
The initial temperature is [tex]T_i = 37 ^oC[/tex]
The final temperature is [tex]T_f = 21^oC[/tex]
The additional precipitate is [tex]m = 0.084 \ kg = 84 \ g[/tex]
Yes because the solubility of the substance X is the amount of X needed to saturate a unit volume of the solvent (for solubility of a solute to be calculated the solute must be able to saturate the solvent)
now we see that the substance X saturated the solvent because a precipitate was formed which the student threw away
The solubility at 21 ° C is mathematically represented as
[tex]S = \frac{m}{m_w * 100 g \ of water }[/tex]
Mass of water([tex]m_w[/tex]) in the solution is mathematically represented as
[tex]m_w = V * \rho_w[/tex]
Where [tex]\rho = 1 \frac{g}{mL}[/tex]
So
[tex]m_w =600 * 1[/tex]
[tex]m_w =600g[/tex]
So
[tex]S = \frac{84}{600 * 100 g \ of water }[/tex]
[tex]S = 0.0014 \ g[/tex]
Real images can be projected onto a screen.
A. True
B. False
Answer:
True
Explanation:
A real image can be projected or seen on a screen but a virtual image cannot because a real image is formed when light rays coming from an object actually meet at a point after refraction through a lens while a virtual image is formed when light rays coming from an object only appear to meet at a point when produced ...
Hope this helps you, and Good luck!
Without doing any calculations, arrange the elements in CF2Cl2 in order of decreasing mass percent composition. Rank from highest percent to lowest.
a. C > F > Cl
b. F < Cl > C
c. Cl > C > F
d. Cl > F > C
Answer:
a. C > F > Cl
Explanation:
We know that atomic mass of Chlorine is greater than of Florine than that of carbon. Moreover, in CF2Cl2, therefore, there are two atoms of Cl, F and one atom of C. Therefore, in CF2Cl2 in order of decreasing mass percent composition C > F > Cl. Therefore, the correct option is a.
a binary ionic compound is made of two components name one of them
Answer:
CATION
Explanation:
It's one is the action and the mother is a cation.
Aqueous hydrobromic acid reacts with solid sodium hydroxide to produce aqueous sodium bromide and liquid water . If of sodium bromide is produced from the reaction of of hydrobromic acid and of sodium hydroxide, calculate the percent yield of sodium bromide.
Answer:
The percentage yield is 50%
The temperature program for a separation starts at a temperature of 50 °C and ramps the temperature up to 270 °C at a rate of 10 °C/minute. Which statement is NOT true for this separation?
A) At 10 °C/minute, a total of 22 minutes is needed to reach 270 oC.
B) Strongly retained solutes will remain at the head of the column while the temperature is low.
C) Weakly retained solutes will separate and elute early in the separation.
D) The vapor pressure of strongly retained solutes will increase as temperature increases.
E) Strongly retained analytes will give broad peaks.
Answer:
The correct answer to the question is Option E (Strongly retained analytes will give broad peaks).
Explanation:
The other options are true because:
A. Initial temp = 50 °C
Final temp = 270 °C
Differences in temp = 270 - 50 = 220°C
Rate = 10 °C/minute.
So, at 10 °C/minute,
total of 220°C /10 °C = number of minutes required to reach the final temp.
220/10 = 22 minutes
B. A column has a minimum and maximum use temperature. Solutes that are already retained would remain stationary while temperatures are low. This would only change if there is an increase in temperature. Heat transfers more energy to the liquid which would make the solute interact with the column phase.
C. Weakly retained solutes may contain larger molecules, will separate by absorbing into the solvent early in separation making the mobile phase separates out into its components on the stationary phase.
D. Retained solute's vapor pressure is higher at higher temperatures making it possible for particle to escape more from the solute when the temperature is high than when it is low.
7.Which one of the following statements is not true?
1 point
O The molecules in a solid vibrate about a fixed position
O The molecules in a liquid are arranged in a regular pattern
The molecules in a gas exert negligibly small forces on each other, except during
collisions
The molecules of a gas occupy all the space available
Answer:
B. the molecules in liquid are loosely packed and scattered thus, they cannot be arranged
Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, write only NR. LiNO₃
Answer:
It is neutral (NR)
Explanation:
Salts are formed when the ionizable hydrogens in an acid is replaced by metallic or ammonium ions from bases. The reaction is known as a neutralization reaction.
The nature of a salt formed from this reaction depends on the nature of the reacting acid and base.
If the reaction is between a strong acid and strong base, the salt produced is a neutral salt.
If the reaction occurs between a strong acid and a weak base, the salt produced is acidic.
If the reaction occurs between a strong base and a weak acid, the salt produced is a basic salt.
Considering the salt above, LiNO3.
On hydrolysis, addition of water, the following products are obtained:
LiNO3 + H2O ----> LiOH + HNO3
The products obtained, LiOH and HNO3 are a strong base and a strong acid respectively. Therefore, the salt, LiNO3, is a neutral salt.
The salt, LiNO₃ is a neutral, NR salt as it's a salt formed from the reaction of a strong acid and a strong base.
In neutralisation reactions, acids and bases react to form salt and water.
However, the salt formed may be acidic, basic or neutral. This is dependent on the type of acid and base which form the salt.
A strong acid and a strong base react to yield a neutral salt like, LiNO₃.
The equilibrium equation when LiNO₃ is dissolved in aqeous solution is;
LiNO₃ + H2O ==>. LiOH + HNO₃Evidently, LiOH and HNO₃ are an example strong base and acid respectively.
Read more:
https://brainly.com/question/2254059
A compound D with the molecular formula C6H12 is optically inactive but can be resolved into enantiomers. On catalytic hydrogenation, D is converted to E (C6H14) and E is optically inactive. Propose structures for D and E. (Draw a three-dimensional formula for each using dashes and wedges around chiral centers.)
Answer:
D: CH2=CH-CH(CH3)-CH2-CH3 (R & S enantiomers)
E: CH3-CH2-(CH3)-CH2-CH3
(Please see the figures enclosed )
Explanation:
D is a racemic mixture (R & S) of 3-metyl-pent-1-ene, so it is optically inactive (although each of two enantiomers is optically active, the mixture is optically inactive. The reason is that two enantiomers are present in an equal amount).
E is optically inactive, so its structure has to be symmetric.
Of the following three atoms, one tends to lose three electrons, another tends to lose two electrons, and another tends to lose one electron. Rank these atoms in order of the number of electrons they tend to lose, from most to fewest: potassium, K; calcium, Ca; gallium, Ga. Rank from most to fewest.
Answer: Ga > Ca > K
Explanation:
Electronic configuration represents the total number of electrons that a neutral element contains. We add all the superscripts to know the number of electrons in an atom.
The electrons are filled according to Afbau's rule in order of increasing energies. The metals tend to get stable by losing electrons to attain noble gas configuration.
[tex]K:19:1s^22s^22p^63s^23p^64s^1[/tex]
[tex]K^+:18:1s^22s^22p^63s^23p^6[/tex]
[tex]Ca:20:1s^22s^22p^63s^23p^64s^2[/tex]
[tex]Ca^{2+}:18:1s^22s^22p^63s^23p^6[/tex]
[tex]Ga:31:1s^22s^22p^63s^23p^64s^23d^{10}4s^24p^1[/tex]
[tex]Ga^{3+}:28:1s^22s^22p^63s^23p^64s^23d^{10}[/tex]
Thus gallium (Ga) loses three electrons, Calcium (Ca) loses 2 electrons and Potassium (K) loses one electron.
a gas obeys the equation of state p(v-b)=RT.for the gas b=0.0391L/mol.calculate the fugacity coefficient for the gas at 1000°c and 1000atm
Answer:
The fugacity coefficient is [tex][\frac{f}{p} ] = 1.45[/tex]
Explanation:
From the question we are told that
The gas obeys the equation [tex]p(v-b) = RT[/tex]
The value of b is [tex]b = b = 0.0391 \ L /mol[/tex]
The pressure is [tex]p = 1000 \ atm[/tex]
The temperature is [tex]T= 1000^oC = 1273 K[/tex]
generally
[tex]RT ln[\frac{f}{p} ] = \int\limits^{p}_{o} [ {v_{r} -v_{i}} ]\, dp[/tex]
Where [tex]\frac{f}{p}[/tex] is the fugacity coefficient
[tex]v_r[/tex] is the real volume which is mathematically evaluated from above equation as
[tex]v_r = \frac{RT}{p} + b[/tex]
[tex]v_r = \frac{RT}{p} + 0.0391[/tex]
and [tex]v_{i}[/tex] is the ideal volume which is evaluated from the ideal gas equation (pv = nRT , at n= 1) as
[tex]v_{i} = \frac{RT}{p}[/tex]
So
[tex]RT ln[\frac{f}{p} ] = \int\limits^{1000}_{o} [[ \frac{RT}{p} + 0.0391] - [\frac{RT}{p} ]} ]\, dp[/tex]
=> [tex]RT ln[\frac{f}{p} ] = \int\limits^{1000}_{o} [0.391 ]\, dp[/tex]
=> [tex]RT ln[\frac{f}{p} ] = [0.391p]\left | 1000} \atop {0}} \right.[/tex]
=> [tex]RT ln[\frac{f}{p} ] = 38.1[/tex]
So
[tex]ln[\frac{f}{p} ] = \frac{39.1}{RT}[/tex]
Where R is the gas constant with value [tex]R = 0.082057\ L \cdot atm \cdot mol^{-1}\cdot K^{-1}[/tex]
[tex][\frac{f}{p} ] = \frac{39.1}{ 2.303 *0.082057 * 1273}[/tex]
[tex][\frac{f}{p} ] = 1.45[/tex]
One proposed mechanism of the reaction of HBr with O2 is given here. HBr + O2 → HOOBr (slow) HOOBr + HBr → 2HOBr (fast) HOBr + HBr → H2O + Br2 (fast) What is the equation for the overall reaction?
Answer:
4 HBr + O2 → + 2H2O + 2Br2
Explanation:
Based on the following reaction mechanism:
HBr + O2 → HOOBr (slow)
HOOBr + HBr → 2HOBr (fast)
HOBr + HBr → H2O + Br2 (fast)
The equation for the overall reaction is the sum of the three reactions in which intermediaries of reaction (HOBr and HOOBr are canceled). That is 1 + 2 + 2*(3):
HBr + O2 + HOOBr + HBr + 2HOBr + 2HBr → HOOBr + 2HOBr + 2H2O + 2Br2
4 HBr + O2 → + 2H2O + 2Br2Beeing this reaction the equation of the overall reaction.