calculate the difference in slope of the chemical potential against temperature on either side of the normal freezing point of water and the normal boiling point of water the molar entropy change accompanying fussion is 22.0 and that accompanying evaporation

Answers

Answer 1

Answer:

(a) The normal freezing point of water (J·K−1·mol−1) is [tex]-22Jmole^-^1k^-^1[/tex]

(b) The normal boiling point of water (J·K−1·mol−1) is [tex]-109Jmole^-^1K^-^1[/tex]

(c) the chemical potential of water supercooled to −5.0°C exceed that of ice at that temperature is  109J/mole

Explanation:

Lets calculate

(a) - General equation -

      [tex](\frac{d\mu(\beta )}{dt})p-(\frac{d\mu(\alpha) }{dt})_p[/tex] = [tex]-5_m(\beta )+5_m(\alpha )[/tex] =  [tex]-\frac{\Delta H}{T}[/tex]

 [tex]\alpha ,\beta[/tex] → phases

ΔH → enthalpy of transition

T → temperature transition

 [tex](\frac{d\mu(l)}{dT})_p -(\frac{d\mu(s)}{dT})_p[/tex] =[tex]= -\frac{\Delta_fH}{T_f}[/tex]

            = [tex]\frac{-6.008kJ/mole}{273.15K}[/tex] ( [tex]\Delta_fH[/tex] is the enthalpy of fusion of water)

           = [tex]-22Jmole^-^1k^-^1[/tex]

(b) [tex](\frac{d\mu(g)}{dT})_p-(\frac{d\mu(l)}{dT})_p= -\frac{\Delta_v_a_p_o_u_rH}{T_v_a_p_o_u_r}[/tex]

                                  = [tex]\frac{40.656kJ/mole}{373.15K}[/tex] ([tex]\Delta_v_a_p_o_u_rH[/tex] is the enthalpy of vaporization)

                               = [tex]-109Jmole^-^1K^-^1[/tex]

(c) [tex]\Delta\mu =\Delta\mu(l)-\Delta\mu(s)[/tex] =[tex]-S_m\DeltaT[/tex]

[tex][\mu(l-5[/tex]°[tex]C)-\mu(l,0[/tex]°[tex]C)][/tex] =  [tex][\mu(s-5[/tex]°[tex]C)-\mu(s,0[/tex]°[tex]C)][/tex][tex]=-S_m[/tex]ΔT

[tex]\mu(l,-5[/tex]°[tex]C)-\mu(s,-5[/tex]°[tex]C)=-Sm\DeltaT [\mu(l,0[/tex]

[tex]\Delta\mu=(21.995Jmole^-^1K^-^1)\times (-5K)[/tex]

     = 109J/mole


Related Questions

What is the volume of 0.200 moles of O2 gas at STP?

Answers

Answer:

4.48 L O2

Explanation:

At STP, a mole of any gas contains 22.4 liters. Therefore, we simply have to multiply the amount of moles by 22.4

0.2mol O2 ( 22.4 L) = 4.48 L O2

Options:
1. Unsaturated fat or saturated fat
2. Fatty acids, carbohydrates, sterols, or phospholipids
3. Fatty acids, carbohydrates, or triglycerides
Please helppp

Answers

Answer:

1. saturated

2. fatty acids

3. fatty acids

Explanation:

Answer:

option 2 is correct

Explanation:

Using current genetic engineering techniques can provide potential benefits for parents, including
A.
eliminating all genetic diseases from their child.
B.
conceiving a child who is a bone marrow match to a living child.
C.
cloning a parent to produce a child identical to the parent.
D.
producing only children with blonde hair.

Answers

Answer:

B. Conceiving a child who is a bone marrow match to a living child.

Explanation:

I don't know it just is.

True or False. The scientific method is a rigid process?

Answers

The answer to your question is true

The statement "The scientific method is a rigid process" is false.

What is scientific method ?

The method by which scientist search for solutions and answers to their problem and question with the help of procedure is called scientific method.

To learn more about scientific method here.

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daily routine care of farm animal husbandry​

Answers

Hey sorry I just need the points!!

Calculate the volume of 0.10 M sucrose solution that must be diluted to prepare 10.00 ml of a 0.015 M sucrose solution

Answers

The solution is 6.0 8ML

What type of Weathering is important to sand storms on Mars? Physical or
Chemical?

Why would 3D printing be important on Mars and why would you use material from the surface of Mars.

We could "print" things that we need on Mars.
We could print things that we need on Mars and use material that is already on the planet
It would be so cool
The cost would be less expensive.

Answers

Answer:

1. Physical Weathering

2. Option B

Explanation:

1. Physical weathering

On Mars, there are two types of weathering agents a) wind and b) acid fog. Thus, they will carry out only physical weathering

2. Option B

3D can be used to produce things that are required on the Mars and also the locally available raw material can be used for printing thereby saving the cost.

List three forms of energy.

Answers

The different types of energy include thermal energy, radiant energy, chemical energy, nuclear energy, electrical energy, motion energy, sound energy, elastic energy and gravitational energy.

you could use any of these.

Answer: Chemical energy is energy stored in the bonds of atoms and molecules. ...

Mechanical energy is energy stored in objects by tension. ...

Nuclear energy is energy stored in the nucleus of an atom—the energy that holds the nucleus together.

Explanation:

List three ways in which the octet rule can sometimes fail to be obeyed

Answers

Answer:

1. Electron-deficient molecules

2. Odd electron molecules

3. Expanded valence shell molecules

Explanation:

I need help with level 15 in covalent bonding in playmada collisions app.

Answers

which level are u on now?

Which of the following molecules are Polar? Select all that apply.
Group of answer choices
A.CH3Cl
B.HF
C.O2
D.PF5
E.HCN
F.SeBr6
G.H2S

Answers

The molecule that is polar is B C G

Calculate the total amount of energy required to change 10.0 g of water from 35.0 degrees Celsius to 110. degrees Celsius.

Answers

Answer:

The total amount of energy required is 25,515.2 J.

Explanation:

Calorimetry is the measurement and calculation of the amounts of heat exchanged by a body or a system.

When a system absorbs (or gives up) a certain amount of heat, it can happen that:

experience a change in its temperature, which involves sensible heat, undergoes a phase change at constant temperature, or latent heat.

To calculate the latent heat the formula is used:

Q = m. L

Where

Q: amount of heat m: mass L: latent heat

To calculate sensible heat the following formula is used:

Q = m. c. ΔT

where:

Q: amount of sensible heat  m: body mass c: specific heat of the substance ΔT: temperature range

In this case, you have in the first place a heat to raise the temp of the water from 35.0 C to 100 C, where the specific heat value for water is  4.184 [tex]\frac{J}{g*C}[/tex]:

q1 = m*c*(Tfinal-Tinitial)

q1 = 10.0 g *(4.184 [tex]\frac{J}{g*C}[/tex])* (100 - 35.0 C) = 2719.6 J

Now you have the heat to vaporize the water, where the heat of vaporization is 2259.36 [tex]\frac{J}{g}[/tex]:

q2 = m*(heat of vaporization)

q2 = 10.0 g*(2259.36 [tex]\frac{J}{g}[/tex]) = 22593.6 J

Finally, you have the heat to raise temp of steam to 110 C, where the specific heat value for steam is  2.02 [tex]\frac{J}{g*C}[/tex] :

q3 = m*c*(Tfinal-Tinitial)

q3 = 10.0 g*(2.02 [tex]\frac{J}{g*C}[/tex])*(110-100 C) = 202 J

The total amount of energy can be calculated as:

Q= q1 + q2 + q3

Q= 2719.6 J + 22593.6 J + 202 J

Q=25,515.2 J

The total amount of energy required is 25,515.2 J.

What keeps the Earth orbiting on its current path
in our solar system?

Answers

gravity is the correct answer
Gravitational pull I think

Why do you think there are different stars in each nighttime section of the artifact?

Answers

Answer:

The sky looks different in each nighttime section of the artifact because the artifact sections represent different seasons. ... Different constellations are visible on different nights throughout the year because of the earth's orbit. The Earth orbits around the sun. A full orbit is 365 days or one year.

Explanation:

Which of the following forces has the smallest energy per bond?
A) iconic bonds
B) covalent bonds
C) hydrogen bonds
D) dispersion bonds

Answers

......A) iconic bonds........

The attractive forces existing between the molecules of a substance are known as the intermolecular forces. Among the given forces dispersion bonds has the smallest energy per bond. Thus option D is correct.

What is Dispersion forces?

The forces which are found in nonpolar molecules like O₂, N₂, Cl₂ etc. as well as in monoatomic gases such as 'He', 'Ne' etc. are called dispersion forces or London forces.

The London force is found to be the weakest intermolecular force and it is known to operate in all types of molecules. This force is also called the induced dipole - induced dipole attraction.

This force is generally resulted from the movement of electron cloud which creates a temporary instantaneous dipole. This distorts the arrangement of electrons of other atoms or molecules which are close to it and also induces a dipole in them.

In this way a large number of nonpolar molecules become polar temporarily and they are attracted by weak attractive forces. The dispersion bonds are easy to form and break.

The dispersion force is the weak attractive force and has the smallest energy per bond.

Thus the correct option is D - Dispersion bonds.

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Which factor contributes the most to the rates of diffusion and effusion between two gases in a mixture?
a)The size of the particles.
b)The molar mass of the particles.
c)The interactions between the particles.
d)The relative volume of the particles to each other.

Answers

Answer:

b)The molar mass of the particles.

Explanation:

The rate of effusion of a gas is inversely proportional to the square root of its molar mass (Graham's law), a relationship that closely approximates the rate of diffusion. As a result, light gases tend to diffuse and effuse much more rapidly than heavier gases.

3. Pepsi puts 355 ml of soda in a can. How many drops is this?

Answers

here’s what i found on the web hope this helped you!:)))

A student dissolves 10.7 g of lithium chloride (LiCl) in 300. g of water in a well-insulated open cup. He then observes the temperature of the water rise from 22.0 °C to 28.6 °C over the course of 3.8 minutes. Use this data, and any information you need from the ALEKS Data resource:
LiCl(s) rightarrow Li+(aq) + Cl-(aq)
You can make any reasonable assumptions about the physical properties of the solution. Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction.
1) Is this reaction exothermic, endothermic, or neither?
2) If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in this case.
3) Calculate the reaction enthalpy delta Hrxn per mole of LiCl.

Answers

Answer:

1) Exothermic.

2) [tex]Q_{rxn}=-8580J[/tex]

3) [tex]\Delta _rH=-121.0kJ/mol[/tex]

Explanation:

Hello there!

1) In this case, for these calorimetry problems, we can realize that since the temperature increases the reaction is exothermic because it is releasing heat to solution, that is why the temperature goes from 22.0 °C to 28.6 °C.

2) Now, for the total heat released by the reaction, we first need to assume that all of it is absorbed by the solution since it is possible to assume that the calorimeter is perfectly isolated. In such a way, it is also valid to assume that the specific heat of the solution is 4.184 J/(g°C) as it is mostly water, therefore, the heat released by the reaction is:

[tex]Q_{rxn}=-m_{Total}C(T_2-T_1)\\\\Q_{rxn}=-(300g+10.7g)*4.184 \frac{J}{g\°C} (28.6\°C-22.0\°C)\\\\Q_{rxn}=-8580J[/tex]

3) Finally, since the enthalpy of reaction is calculated by dividing the heat released by the reaction over the moles of the solute, in this case LiCl, we proceed as follows:

[tex]\Delta _rH=\frac{Q_{rxn}}{n_{LiCl}} \\\\\Delta _rH=\frac{-8580J}{10.7g*\frac{1mol}{150.91g} }*\frac{1kJ}{1000J} \\\\\Delta _rH=-121.0kJ/mol[/tex]

Best regards!

Question 9 of 10
Which of the following statements are true of nuclear energy and reactors?
Check all that apply.
O A. Nuclear reactors on Earth use fusion reactions to produce energy.
B. Nuclear fission reactions use only a small amount of material to
produce a large amount of energy.
C. Nuclear reactors use controlled reactions.
D. Nuclear fission is done by joining nuclei together into a bigger
nucleus.

Answers

Answer:

B. Nuclear fission reactions use only a small amount of material to

produce a large amount of energy.

C. Nuclear reactors use controlled reactions.

Explanation:

Nuclear reactors are devices that contain and control nuclear chain reactions while releasing heat produced from these nuclear chain reactions at a controlled rate.

A nuclear power plant uses the enormous amount of heat that are produced from the nuclear chain reactions occurring in the nuclear reactor to turn water into steam, which then drives turbine generators that generate electricity.

The nuclear chain reactions occurring in the nuclear reactor are fission chain reactions. A nuclear fission reaction is a reaction in which a larger atom is split into two or more smaller atoms when bombarded with energetic neutrons resulting in the release of large amounts of energy and more neutrons. The neutrons released split more atoms of the larger atom into smaller atoms in what is known as a chain reaction. This reaction is controlled by means of moderators. A moderator helps slow down the neutrons produced by fission to sustain the chain reaction.

Statements that are right as regards nuclear energy and reactors are ;

B. Nuclear fission reactions use only a small amount of material to

produce a large amount of energy.

C. Nuclear reactors use controlled reactions.

Nuclear fission can be regarded as splitting of a large atomic nucleus into smaller nuclei, in this case neutron is absorbed into a nucleus. It utilize small material to produce energy.

This process is done by the use of nuclear reactor which brings about a  controlled reaction.

Therefore option B,C, are correct.

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what are the reasons that you cannot see many stars in the city nights?

Answers

Answer:

Because of the artificial lights influencing the dark night, turning it into a grey.

4
The work done when a gas is compressed in a cylinder is 338 J. At the same time,
it absorbs 142 J of heat from the surroundings. Compute the change in energy of
the system.

Answers

Answer:

bbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbb

Explanation:

kh uh

What is factor that is covered up by another trait Dominant or recessive

Answers

Answer: Recessive

Explanation: The recessive trait is often faded away by the dominant/other

Also looking at the word dominant it means powerful, most important, influential meaning it would most likely overpower

Goodluck :)

How many moles of Cs are contained in 3 moles of Cs3PO4?

Answers

Answer:

[tex]\boxed {\boxed {\sf 9 \ moles \ Cs}}[/tex]

Explanation:

We are given the compound: Cs₃PO₄

According to the formula, 1 mole of cesium phosphate contains 3 moles of cesium, 1 mole of phosphate, and 4 moles of oxygen.

Therefore, there are 3 moles of cesium for 1 mole of cesium phosphate.

[tex]\frac {3 \ mol \ Cs}{1 \ mol \ Cs_3PO_4}[/tex]

We want to calculate the moles of cesium in 3 moles of cesium phosphate, so we multiply the ratio by 3.

[tex]3 \ mol \ Cs_3PO_4 *\frac {3 \ mol \ Cs}{1 \ mol \ Cs_3PO_4}[/tex]

[tex]3 *\frac {3 \ mol \ Cs}{1 }= 9 \ mol \ Cs[/tex]

3 moles of cesium phosphate contains 9 moles of cesium.

How does a tree get energy?
A. It does not need energy
B. It gets energy from the Sun.
C. It eats food in its environment.

Answers

The correct answer is b

WILL GIVE THE BRAINLIEST!!! help me pls

Answers

Answer:

Two of them are solids, one is liquid. Two of them are edible, one is not. One is a mixture, and two are not.

Explanation:

What are the final units when you have a mass (in grams), and then divide it by molar
mass

Answers

Answer:

The final units are mol

Explanation:

The units of molar mass are grams per mole, g/mol.

This means that when dividing mass by molar mass, the units of grams cancel each other, leaving only units of moles:

Grams ÷ Grams/mol

Another way of writing that might help is as follows:

[tex]\frac{g}{\frac{g}{mol}}[/tex]

Thus, the final units are moles.

4.00 g of O2 gas are in a sealed, 2.00 L gas canister at 22.0 °C what is the pressure inside this container (in atm)?

Answers

Answer:

1.51448 atms

Explanation:

3. The name of the functional group in the following compound
CH3 - CH2 - CH2 - CH-CH2 - CH3
1
CH3 – CH2
a. Methyl
b. Ethyl
C. Propyl
d. Isopropy!

Answers

Answer: a.) Methyl would be the answer.

Explanation:

2. What human-related environmental
factors might also be affecting the
growth of the toxic algae?

Answers

Answer:

Polution

Explanation:

If a piece of silver specific heat .2165 j/g °C with a mass of 14.16 g and a temperature of 133.5°C is dropped into 250.0 g of fat 17.20°C what will be the final temperature of the system

Answers

Answer:

[tex]T_F=17.56\°C[/tex]

Explanation:

Hello there!

In this case, for this calorimetry problem, it is possible for us to realize that the heat lost by the hot silver is gained by the cold far whose specific heat is 3.94 J/g°c, so we can write:

[tex]-Q_{Ag}=Q_{fat}[/tex]

Which can be written in terms of mass, specific heat and temperature as shown below:

[tex]-m_{Ag}C_{Ag}(T_F-T_{Ag})=m_{fat}C_{fat}(T_F-T_{fat})[/tex]

In such a way, solving for the final temperature, we obtain:

[tex]T_F=\frac{m_{Ag}C_{Ag}T_{Ag}+m_{fat}C_{fat}T_{fat}}{m_{Ag}C_{Ag}+m_{fat}C_{fat}}}[/tex]

Then, we plug in the given data to obtain:

[tex]T_F=\frac{14.16g*0.2165J/g\°C*133.5\°C+250g*3.94J/g\°C*17.20\°C}{14.16g*0.2165J/g\°C+250g*3.94J/g\°C} \\\\T_F=17.56\°C[/tex]

Best regards!

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