determine the empirical and molecular formula of a compound which has the molecular mass of 90grams/mole, which contains 80.0% carbon and 20% hydrogen

Answers

Answer 1

Answer :

Empirical formula : CH3

Molecular Formula : C6H18

Explanation :

C : H

80/ 12 : 20/ 1

6.67/ 6.67 : 20/ 6.67

1 : 3

Therefore : CH3

Molecular formula :

First calculate n

n = Relative molecular mass / Empirical formula mass

= 90/15

= 6

Therefore : ( CH3) subscript 6

= C6H18


Related Questions

you added 20 ml of 0.20m solution of ba(oh)2(aq) to 50 ml of 0.10m solution of hcl(aq). the ph of the resulting solution is .

Answers

When the mmol of OH - ions and mmol of H + ions is calculate the pH = 12.6 and volume of solution = 0.0428 M

We can take care of given issue in following advances. Evaluating of mmol of OH - ions and mmol of H + ions.

mmol of  Ba(OH)₂ = Concentration × Volume

                                0.20 M × 20 ml

                                    = 4 mmol

1 molecule of Ba(OH)₂ contain two OH - ions.

Therefore, mmol of OH - ions = 2 × ( mmol of  Ba(OH)₂

                                              = 8 mmol

mmol of H + ions = 0.10 M × 50 ml = 5.0 mmol

Determination of the excess reactant concentration and amount :

Consider reaction, H⁺ + OH⁻ → H₂O  

According to the  reaction, 1 mmol H⁺ reacts with 1 mmol OH⁻.  

therefore 5.0 mmol H + reacts with 5 mmol OH⁻ .  

Hence, excess mmol of  OH⁻ = 8.0 - 5.0

                                             = 3.0 mmol

Volume of solution = 20 ml + 50 ml = 70 ml

[ OH⁻ ] = 3.0 mmol / 70 ml

                 = 0.0428 M

Calculation of pH :

We will have relation, pOH = - log [ OH⁻ ]

pOH= - log 0.0428

pOH = 1.41

We got relation, pH = 14 - pOH

          pH = 14 -1.41

             pH = 12.6

pH characterizes as :

"Potential of hydrogen" has historically been associated with pH, which is also known as acidity. An aqueous solution's acidity or basicity can be measured using this scale. Acidic arrangements are estimated to have lower pH values than essential or antacid arrangements

Overabundance reactant :

An overabundance reactant is a reactant present in a sum in abundance of that expected to consolidate with the entirety of the restricting reactant. After the limiting reactant has been used up, an excess reactant is what remains in the reaction mixture.

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Which of the following compounds is likely to produce a solution that conducts electricity (strong electrolyte) when dissolved in water? a) CH3CH₂OH b) SrCO3 c) SCl₂ d) K₂SO4

Answers

The compound most likely to produce a solution that conducts electricity (strong electrolyte) when dissolved in water is d) K₂SO₄. This is because K₂SO₄ is an ionic compound that dissociates into its ions when dissolved in water, allowing the solution to conduct electricity effectively. The other compounds listed are either molecular compounds or have limited solubility in water, which makes them less likely to form strong electrolytes.

Out of the four given compounds, K₂SO4 is likely to produce a solution that conducts electricity (strong electrolyte) when dissolved in water. This is because K₂SO4 dissociates into K⁺ and SO₄²⁻ ions in water, which are both charged and can move freely in the solution, allowing for the flow of electric current. On the other hand, CH3CH₂OH and SrCO3 are covalent and ionic compounds respectively, but they do not dissociate into charged ions in water to conduct electricity. SCl₂ is also a covalent compound, but it can hydrolyze in water to produce HCl, which conducts electricity to some extent.

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the complex ion [co(h2o)6]3 is blue in an aqueous solution. estimate the wavelength of maximum absorbance.
a) 200 nm
b) 300 nm
c) 400 nm
d) 600 nm
e) 800 nm

Answers

The complex ion[tex][Co(H_2O)_6]^3^+[/tex] exhibits a blue color in aqueous solution. The estimated wavelength of maximum absorbance for this complex ion is around 600 nm.

The color of transition metal complexes arises from the absorption of specific wavelengths of light due to electronic transitions in the metal ions. In the case of the complex ion [tex][Co(H_2O)_6]^3^+[/tex], the cobalt [tex](Co)[/tex] ion is surrounded by six water [tex](H_2O)[/tex] ligands. The absorption of light by this complex ion results in the blue color observed in an aqueous solution.

To estimate the wavelength of maximum absorbance, we can refer to the concept of complementary colors. The color observed corresponds to the wavelength of light that is least absorbed by the complex ion. Since blue is complementary to yellow, which has a wavelength of around 600 nm, we can estimate that the maximum absorbance for[tex][Co(H_2O)_6]^3^+[/tex]occurs around 600 nm.

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ased on the following reaction: bacl2(aq) na2so4(aq) → baso4(s) 2 nacl(aq) if a reaction mixture contains 4.16 g of bacl2 and 3.30 g of na2so4 how many moles of the precipitate will be formed?

Answers

Apprοximately 0.02 mοles οf the precipitate (BaSO₄) will be fοrmed.

How tο determine the number οf mοles ?

Tο determine the number οf mοles οf the precipitate (BaSO₄) fοrmed in the reactiοn between BaCl₂ and Na₂SO₄, we need tο cοmpare the reactants' mοles and use the stοichiοmetry οf the balanced equatiοn.

The balanced equatiοn fοr the reactiοn is:

BaCl₂(aq) + Na₂SO₄(aq) → BaSO₄(s) + 2NaCl(aq)

Frοm the equatiοn, we can see that 1 mοle οf BaCl₂ reacts with 1 mοle οf Na₂SO₄ tο prοduce 1 mοle οf BaSO₄.

First, we need tο calculate the number οf mοles οf BaCl₂ and Na₂SO₄ present in the reactiοn mixture using their respective mοlar masses.

The mοlar mass οf BaCl₂ is calculated as:

Mοlar mass οf BaCl₂ = (1 * 137.33 g/mοl) + (2 * 35.45 g/mοl) = 208.23 g/mοl

The mοlar mass οf Na₂SO₄ is calculated as:

Mοlar mass οf Na₂SO₄ = (2 * 22.99 g/mοl) + 32.06 g/mοl + (4 * 16.00 g/mοl) = 142.04 g/mοl

Nοw, let's calculate the number οf mοles fοr each reactant:

Mοles οf BaCl₂ = mass οf BaCl₂ / mοlar mass οf BaCl₂

= 4.16 g / 208.23 g/mοl

≈ 0.02 mοl

Mοles οf Na₂SO₄ = mass οf Na₂SO₄ / mοlar mass οf Na₂SO₄

= 3.30 g / 142.04 g/mοl

≈ 0.023 mοl

Based οn the stοichiοmetry οf the balanced equatiοn, 1 mοle οf BaCl₂ reacts with 1 mοle οf Na₂SO₄ tο prοduce 1 mοle οf BaSO₄.

Since the reactiοn is stοichiοmetric, the limiting reactant is the οne with fewer mοles, which in this case is BaCl₂ (0.02 mοl).

Therefοre, the number οf mοles οf BaSO₄ precipitate fοrmed will be equal tο the number οf mοles οf BaCl₂ used:

Number οf mοles οf BaSO₄ = 0.02 mοl

Sο, apprοximately 0.02 mοles οf the precipitate (BaSO₄) will be fοrmed.

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what volume of a 1.0 M solution of KOH can be made with 100 grams of potassium hydroxide?

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To determine the volume of a 1.0 M solution of KOH that can be made with 100 grams of potassium hydroxide, it is necessary to calculate the number of moles of KOH using the formula: mass = moles x molar mass.  A volume of 1.78 liters of a 1.0 M solution of KOH can be made with 100 grams of potassium hydroxide.

Rearranging the formula: moles = mass / molar mass molar mass of KOH (K = 39.1 g/mol; O = 16.0 g/mol; H = 1.0 g/mol)molar mass of KOH = 39.1 + 16.0 + 1.0 = 56.1 g/mol Now, substituting the values in the above formula, moles of KOH = 100 g / 56.1 g/mol= 1.78 mol

Thus, 1.78 mol of KOH is present in 100 g of KOH.To determine the volume of a 1.0 M solution of KOH that can be made with 100 grams of potassium hydroxide, it is necessary to divide the number of moles by the molarity. Thus, Volume of solution = moles / molarity= 1.78 mol / 1.0 mol/L= 1.78 L

Therefore, a volume of 1.78 liters of a 1.0 M solution of KOH can be made with 100 grams of potassium hydroxide.

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Given the electrochemical reaction shown, what is the standard free energy change ΔG° if E˚ = +1.61 V? Mg | Mg2+(aq) || Zn2+(aq) | Zn

Answers

The standard free energy change (ΔG°) for the given electrochemical reaction is approximately -310,000 J/mol.

The electrochemical reaction given is Mg + Zn2+ → Mg2+ + Zn. To calculate the standard free energy change ΔG°, we can use the formula ΔG° = -nFE°, where n is the number of electrons transferred in the reaction, F is the Faraday constant (96,485 C/mol), and E° is the standard electrode potential. In this case, n = 2 because two electrons are transferred in the reaction, and E° = +1.61 V because it is given in the question. Plugging these values into the formula, we get: ΔG° = -2 x 96,485 C/mol x (+1.61 V) = -311,963 J/mol. Therefore, the standard free energy change ΔG° for the given electrochemical reaction is -311,963 J/mol. This indicates that the reaction is spontaneous and releases energy.
The standard free energy change (ΔG°) of an electrochemical reaction can be determined using the Nernst equation:
ΔG° = -nFE°
where n is the number of electrons transferred, F is the Faraday constant (96,485 C/mol), and E° is the standard cell potential.
In the given reaction, Mg is oxidized to Mg2+ and Zn2+ is reduced to Zn:
Mg → Mg2+ + 2e- (oxidation)
Zn2+ + 2e- → Zn (reduction)
The overall reaction is:
Mg + Zn2+ → Mg2+ + Zn
From the balanced equation, we can see that n = 2 electrons are transferred. Given E° = +1.61 V, we can now calculate ΔG°:
ΔG° = -2 * 96,485 C/mol * 1.61 V
ΔG° = -310,000 J/mol
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If a molecule with a central atom that has five regions of electron density has exactly one lone pair of electrons, what will its molecular geometry be?
Select the correct answer below:
A. square planar
B. trigonal pyramid
C. seesaw
D. tetrahedral

Answers

The molecular geometry of a molecule with a central atom that has five regions of electron density and one lone pair of electrons will be seesaw

If a molecule has a central atom with five regions of electron density, it must have a trigonal bipyramidal molecular geometry. This means that the five regions of electron density will be arranged in a symmetrical manner around the central atom, with three of them in the equatorial plane and two of them along the axial axis.
If the molecule has only one lone pair of electrons, it will occupy one of the equatorial positions, resulting in a seesaw molecular geometry. This is because the lone pair takes up more space than the bonded atoms, causing a distortion in the molecule's shape. The molecular geometry of a molecule is important because it affects its physical and chemical properties. For example, the shape of a molecule can affect its polarity, which in turn can affect its reactivity and interactions with other molecules.

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determine what type of reaction each unbalanced chemical equation represents

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The unbalanced chemical equations provided represent various types of reactions, including synthesis, decomposition, single replacement, and double replacement reactions.

1. Synthesis Reaction: A synthesis reaction involves the combination of two or more substances to form a single product. It is represented by the equation:

[tex]\[\text{{Reactant 1}} + \text{{Reactant 2}} \rightarrow \text{{Product}}\][/tex]

2. Decomposition Reaction: In a decomposition reaction, a single reactant breaks down into two or more products. The equation for a decomposition reaction is:

[tex]\[\text{{Reactant}} \rightarrow \text{{Product 1}} + \text{{Product 2}}\][/tex]

3. Single Replacement Reaction: A single replacement reaction occurs when an element replaces another element in a compound. It can be expressed as:

[tex]\[\text{{Reactive Element}} + \text{{Compound}} \rightarrow \text{{New Compound}} + \text{{Replaced Element}}\][/tex]

4. Double Replacement Reaction: A double replacement reaction involves the exchange of ions between two compounds, resulting in the formation of two new compounds. It is depicted by the equation:

[tex]\[\text{{Compound 1}} + \text{{Compound 2}} \rightarrow \text{{New Compound 1}} + \text{{New Compound 2}}\][/tex]

By identifying the patterns and characteristics of the given equations, we can determine the type of reaction represented in each case.

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what wavelength of light is required to dissociate iodine molecules into iodine atoms? (hint: think about the reaction from i2 2 i and remember that only one photon will dissociate 1 molecule.)

Answers

The 4995 A wavelength of light is required to dissociate iodine molecules into iodine atoms.

What is wavelength of light?

The area of the electromagnetic spectrum that is visible to human eyes is known as the visible light spectrum. Simply put, this group of wavelengths is referred to as visible light. Usually, the human eye is capable of detecting wavelengths between 380 and 700 nanometres.

Suppose that,

I₂ (g) ⇄ 2I (g)

The energy required to dissociates 1 mole of Iodine molecule is 57.4 kcal/mol.

Wavelength is,

E = (hc/λ) × Nₐ

Substitute values,

57.4 = {(6.626×10⁻³⁴)(3×10⁸)(6.022×10²³)}/λ

Solve value for λ,

λ = 4995×10⁻¹⁰ m

And after converting,

λ = 4995 A

So, it has been found that gaseous iodine molecule just dissociates into iodine atoms after absorption of lit at wavelength 4995 A.

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calculate the ph of a 0.10 m solution of sodium formate (NaHCOO) given that the Ka of formic acid (HCOOH) is 1.8 x 10^-4.

Answers

The pH of a 0.10 M solution of sodium formate is approximately 4.74.

To calculate the pH of a solution of sodium formate (NaHCOO), we need to consider the dissociation of sodium formate into formate ions (HCOO-) and sodium ions (Na+). The formate ion is the conjugate base of formic acid (HCOOH).

First, let's write the balanced equation for the dissociation of sodium formate in water:

NaHCOO ⇌ HCOO- + Na+

Since sodium formate is a salt, it completely dissociates in water. This means that the concentration of formate ions (HCOO-) is equal to the initial concentration of sodium formate, which is 0.10 M.

Next, we need to consider the equilibrium between formate ions (HCOO-) and formic acid (HCOOH) using the Ka value. The Ka expression for formic acid is:

Ka = [H+][HCOO-] / [HCOOH]

Since we know the Ka value (1.8 x 10⁴), we can rearrange the equation to solve for the concentration of H+ ions ([H+]):

[H+] = (Ka * [HCOOH]) / [HCOO-]

We assume that the concentration of formic acid is equal to the concentration of formate ions, which is 0.10 M.

[H+] = (1.8 x 10⁴ * 0.10) / 0.10

[H+] = 1.8 x 10⁴

Now, we can calculate the pH using the formula:

pH = -log[H+]

pH = -log(1.8 x 10⁴)

pH ≈ 4.74

Therefore, the pH of a 0.10 M solution of sodium formate is approximately 4.74.

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Jayadev has apassion for photography. Maker the there films out of silver chloride which De composes when expos to light write the balanced equation.for the reaction

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The decomposition reaction of silver chloride (AgCl) when exposed to light can be represented by the following balanced equation:

2AgCl (s) → 2Ag (s) + Cl2 (g)

In this equation, solid silver chloride decomposes into silver metal (Ag) and gaseous chlorine (Cl2) when exposed to light.

This reaction is an example of a photochemical reaction, where light energy triggers a chemical change. In this case, the absorption of light energy causes the silver chloride crystal lattice to break down, resulting in the formation of silver atoms and chlorine molecules.

It's worth noting that silver chloride is a photosensitive compound commonly used in traditional black and white photography. When light strikes the silver chloride-coated film, it creates a pattern of exposed and unexposed areas. The exposed areas undergo the decomposition reaction, resulting in the formation of metallic silver, which forms the photographic image.

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what is 4 forces of flight​

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The four forces of flight include the following: lift, thrust, drag, and weight.

What is a force?

A force is defined as an external action on an object that causes it to move from one place to another.

For a airplane to be suspended on air, the four forces that must act on it includes the following:

lift force; the upward acting force;

weight, the downward acting force;

thrust, the forward acting force; and

drag, the backward acting force (also called wind resistance).

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(a) compute the repeat unit molecular weight of polypropylene. (b) compute the number-average molecular weight for polypropylene for which the degree of polymerization is 15,000.

Answers

a) The repeat unit mοlecular weight οf pοlyprοpylene is 42.08 g/mοl.

b) The number-average mοlecular weight οf pοlyprοpylene with a degree οf pοlymerizatiοn οf 15,000 is apprοximately 315,620 g/mοl.

How to compute the molecular weight of polypropylene?

a) The repeat unit οf pοlyprοpylene cοnsists οf the mοnοmer prοpylene, which has a mοlecular weight οf apprοximately 42.08 g/mοl.

Therefοre, the repeat unit mοlecular weight οf pοlyprοpylene is 42.08 g/mοl.

(b) The number-average mοlecular weight (Mn) οf a pοlymer can be calculated using the fοrmula:

Mn = M0 × (1 + 2 + 3 + ... + n) / (n + 1)

where M0 is the mοlecular weight οf the repeat unit and n is the degree οf pοlymerizatiοn.

In this case, M0 (repeat unit mοlecular weight) is 42.08 g/mοl and n (degree οf pοlymerizatiοn) is 15,000.

Mn = 42.08 g/mοl × (1 + 2 + 3 + ... + 15,000) / (15,000 + 1)

Tο calculate the sum οf numbers frοm 1 tο 15,000, we can use the fοrmula fοr the sum οf an arithmetic series:

Sum = (n / 2) × (first term + last term)

Using this fοrmula, we have:

Sum = (15,000 / 2) × (1 + 15,000) = 112,507,500

Nοw we can substitute the values intο the equatiοn fοr Mn:

Mn = 42.08 g/mοl × 112,507,500 / (15,000 + 1)

Mn ≈ 315,620 g/mοl

Therefοre, the number-average mοlecular weight οf pοlyprοpylene with a degree οf pοlymerizatiοn οf 15,000 is apprοximately 315,620 g/mοl.

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Match the correct behavior of ions toward sulfuric acid, H2SO4.
1) Chloride, Cl- ...
A: Violet or red-brown vapors of elemental iodine form
B: colorless, odorless gas (carbon dioxide) evolves
C. Colorless, pungent gas, HCl evolves, which turns blue litmus red
D: No observable reaction

Answers

D: No observable reaction

When chloride ions (Cl-) are added to sulfuric acid (H2SO4), no observable reaction occurs. This is because chloride ions are not strong enough to displace the hydrogen ions (H+) in H2SO4. The hydrogen ions are more attracted to the sulfate ions (SO42-) in the acid, which means that the chloride ions cannot displace them. As a result, there is no chemical reaction and no color change or gas evolution occurs.
It's important to note that the behavior of ions towards sulfuric acid can vary depending on the specific ion and its properties. Some ions may be strong enough to displace the hydrogen ions and react with the acid, while others may not react at all. Understanding the behavior of ions towards sulfuric acid is important in many chemical processes and industries.

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how many electrons are in the valence shell of each atom? (a) carbon (b) nitrogen (c) chlorine (d) aluminum

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The number of valence electrons in the outermost shell for each atom is (a) 4 for carbon, (b) 5 for nitrogen, (c) 7 for chlorine, and (d) 3 for aluminum.

Valence electrons play a crucial role in determining an atom's chemical properties and its ability to form bonds with other atoms.

(a) Carbon: Carbon has four valence electrons in its outermost shell (valence shell). Carbon is located in group 14 of the periodic table, and since it has four valence electrons, it can form four covalent bonds by sharing electrons with other atoms.

(b) Nitrogen: Nitrogen has five valence electrons in its valence shell. It is located in group 15 of the periodic table, meaning it has five electrons in its outermost shell. Nitrogen can form three covalent bonds by sharing electrons, typically aiming to achieve a stable octet configuration.

(c) Chlorine: Chlorine has seven valence electrons in its valence shell. As a halogen in group 17 of the periodic table, chlorine requires only one additional electron to complete its octet. It can achieve this by accepting an electron from another atom or by forming a covalent bond where it shares one electron.

(d) Aluminum: Aluminum has three valence electrons in its valence shell. It is located in group 13 of the periodic table, meaning it has three electrons in its outermost shell. Aluminum tends to lose these three valence electrons to form a 3+ cation, aiming for a stable noble gas configuration.

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name the following compound according to substitutive iupac nomenclature
(CH3)2 CHCH2CH2CH2OH

Answers

The compound (CH3)2CHCH2CH2CH2OH can be named according to substitutive IUPAC nomenclature as 3-methylhexan-3-ol. Therefore, the name of the compound is 3-methylhexan-3-ol.

To break it down, we start by identifying the longest continuous chain of carbon atoms which in this case is six carbons long. The prefix hex- is used to indicate this and the suffix -ol indicates that it is an alcohol group.
Next, we need to indicate the position of the substituents on the carbon chain. The two methyl groups are both attached to the third carbon atom in the chain, hence the prefix 3-methyl-.
Overall, the name of the compound is 3-methylhexan-3-ol.
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Which of the following explains how one of the postulates in John Dalton's atomic theory was later subjected to change?
Choice 1
Various scientists found that all atoms of a particular element are identical
Choice 2
Some scientists found that atoms combine in simple whole number ratios to form compounds.
Choice 3
Various scientists found that atoms consist of subatomic particles with varying mass and charge.
Choice 4
Some scientists found that bonds between atoms are broken, rearranged, or reformed during reactions.

Answers

answer

The answer is **Choice 3**.

steps

Various scientists found that atoms consist of subatomic particles with varying mass and charge. This led to the discovery of protons, neutrons, and electrons which are the subatomic particles that make up atoms. John Dalton's atomic theory was later modified to include these subatomic particles.

Show your work and calculate the total number of cations and anions in the unit cell of: a. Fluorite (CaF2) b. Zinc blende (Zn) Cesium Chloride d. Rock salt (NaCl)

Answers

a. Fluorite (CaF2):

In the unit cell of fluorite (CaF2), there are 2 fluoride ions (F-) for every 1 calcium ion (Ca2+).

Total number of cations = 1 (Ca2+)

Total number of anions = 2 (2F-)

b. Zinc blende (ZnS):

In the unit cell of zinc blende (ZnS), there is 1 sulfur ion (S2-) for every 4 zinc ions (Zn2+).

Total number of cations = 4 (4Zn2+)

Total number of anions = 1 (S2-)

c. Cesium Chloride (CsCl):

In the unit cell of cesium chloride (CsCl), there is 1 chloride ion (Cl-) for every 1 cesium ion (Cs+).

Total number of cations = 1 (Cs+)

Total number of anions = 1 (Cl-)

d. Rock salt (NaCl):

In the unit cell of rock salt (NaCl), there is 1 chloride ion (Cl-) for every 1 sodium ion (Na+).

Total number of cations = 1 (Na+)

Total number of anions = 1 (Cl-)

It's important to note that these calculations are based on the stoichiometry of the compounds and the arrangement of ions in the unit cell.

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What is the stoichiometric factor between N2 and NO in the following balanced chemical equation?
N2+O2?2NO

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The stoichiometric factor between N2 and NO in the balanced chemical equation N2 + O2 → 2NO is 1:2, meaning that 1 mole of N2 reacts to produce 2 moles of NO.

The stoichiometric factor between N2 and NO in the balanced chemical equation N2 + O2 → 2NO is 1:2. In the equation, we see that 1 molecule of N2 reacts with 1 molecule of O2 to produce 2 molecules of NO. The coefficients in front of the compounds represent the stoichiometric ratios, indicating the relative number of molecules or moles involved in the reaction.

Therefore, for every 1 molecule of N2, we obtain 2 molecules of NO. This ratio of 1:2 is the stoichiometric factor between N2 and NO in the given balanced chemical equation

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Explain why resonance between the O-C-O atoms that make up the ester functionality doesn't exist if any of these three atoms are sp3 hybridized.

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Resonance occurs when there are multiple valid Lewis structures that can represent a molecule or ion. These resonance structures differ only in the arrangement of electrons, while the connectivity of atoms remains the same. Resonance stabilization typically leads to enhanced stability and delocalization of electrons.

In the case of the ester functionality, which consists of an oxygen atom bonded to a carbon atom through a double bond, the presence of resonance can influence the chemical properties of the molecule. However, resonance between the O-C-O atoms in the ester group does not exist when any of these three atoms are sp³ hybridized. Here's why:

In order for resonance to occur, the atoms involved need to have unhybridized p orbitals available for electron delocalization. In sp³ hybridization, one s orbital and three p orbitals are combined to form four sp³ hybrid orbitals. These hybrid orbitals are then used to form sigma bonds with other atoms.

In the case of oxygen and carbon atoms in the ester functionality, when they are sp³ hybridized, all of their available orbitals are involved in sigma bonds. The p orbitals, which are required for resonance, are not available in sp³ hybridized atoms because they have been hybridized into sp³ orbitals.

Without unhybridized p orbitals, the electrons cannot move and participate in resonance between the O-C-O atoms. As a result, the ester functionality does not exhibit resonance when any of these atoms are sp³ hybridized.

Resonance between the O-C-O atoms in the ester functionality does not exist if any of these three atoms (oxygen or carbon) are sp3 hybridized. This is because sp3 hybridized atoms do not have the necessary p orbitals required for the formation of pi bonds, which are essential for resonance.

Resonance occurs when a molecule or ion can be represented by multiple Lewis structures, with the electrons delocalized or spread out over the molecule. In the case of the ester functionality, resonance is typically observed between the oxygen and carbon atoms within the carbonyl group (C=O) and the adjacent oxygen atom.

To participate in resonance, the atoms involved must have overlapping p orbitals to form pi bonds and delocalize electrons. However, sp3 hybridized atoms, such as those in tetrahedral carbon or oxygen, do not have p orbitals available for pi bonding. The four sigma bonds formed by sp3 hybrid orbitals are directed towards the corners of a tetrahedron, leaving no p orbitals for pi bond formation.

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for the reaction: agi(s) br2(g) → agbr(s) i2(s) δh° = –54.0 kj δhf° for agbr(s) = –100.4 kj/mol δhf° for br2(g) = 30.9 kj/mol the value of δhf° for agi(s) is:

Answers

Any element's natural Hf value is zero. In the given reaction the enthalpy value for AgI = -61.85 kJ/mol

The reaction is :

                             AgI + 1/2Br₂ ---> AgBr + 1/2 I₂

H Rxn = H products - H reactants

HRxn =  AgBr + 1/2 I₂ - (AgI + 1/2Br₂)

substituting known data :

-54 = -100.4 + 1/2 × 0 - (AgI + 1/2 × (30.9))

solving for AgI :

AgI =  -100.4  + 54 -  1/2 ×  (30.9)

AgI = -61.85 kJ/mol

Hess's law :

According to Hess's law, a chemical reaction's change in enthalpy is the same whether it occurs in one step or several, as long as the reactants' and products' initial and final states are the same. Since enthalpy is an extensive property, its value is inversely proportional to the size of the system. Along these lines, the enthalpy change is corresponding to the quantity of moles partaking in a given response.

What is a level chemistry Hess's law?

According to Hess's Law, the path taken by a chemical reaction has no effect on the enthrall change. This indicates that no matter how many steps are taken, the enthalpy change for the entire process will remain the same.

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The balanced equation Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(8) can be interpreted to mean that ? a)1 mol of Fe reacts with 2 mol of HCL b)1 mol of Fe reacts to produce 2 mol of FeCl2 c) 2 g of HCl reacts to produce 1 g of H2 4)1 g of Fe reacts to produce 1 g of FeCl2

Answers

The correct interpretation of the balanced equation Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g) is: a) 1 mol of Fe reacts with 2 mol of HCl.

Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, just ahead of oxygen, forming much of Earth's outer and inner core

This interpretation is based on the stoichiometric coefficients in the balanced equation. It shows the molar ratio between Fe and HCl, indicating that for every 1 mole of Fe, 2 moles of HCl are consumed in the reaction.

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What is the product formed from the following acid base reaction when ammonia functions as a base? the equilibrium lies far to the reactants.
CH3OH+ NH3

Answers

The product formed from the acid-base reaction between CH3OH and NH3, with ammonia acting as a base, is CH3O- (methoxide ion).



The reaction is as follows  CH3OH + NH3 ⇌ CH3O- + NH4+
In this reaction, the methanol donates a proton (H+) to ammonia, resulting in the formation of a methoxide ion (CH3O-) and an ammonium ion (NH4+). The equilibrium of this reaction is determined by the relative strengths of the acid and base involved. As you mentioned, the equilibrium lies far to the reactants' side, meaning that the reaction favors the formation of methanol and ammonia. This indicates that the reactants are relatively weak in their acid and base properties, and the reaction doesn't proceed significantly toward the products. In such a scenario, only a small amount of methoxide (CH3O-) and ammonium (NH4+) ions are formed.

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Based on the crystal-field strengths Cl– < F– < H2O < NH3 < H2NC2H4NH2, which octahedral titanium(III) complex below has its d-d electronic transition at the shortest wavelength?
a. [Ti(OH2)6]3+
b. [TiF6]3–
c. [Ti(H2NC2H4NH2)3]3+
d. [Ti(NH3)6]3+
e. [TiCl6]3–

Answers

The octahedral titanium (III) complex having d-d electronic transition at the shortest wavelength among the given octahedral complexes is [TiF6]3–.

According to the spectrochemical series, the octahedral complex with the weakest field ligand will absorb light with the lowest energy and will exhibit a lower frequency d-d transition. This means that a low frequency corresponds to a long wavelength and high energy corresponds to a short wavelength. So, the octahedral titanium (III) complex having d-d electronic transition at the shortest wavelength among the following is [TiF6]3–.Reasoning

In octahedral complexes, d-d electronic transitions occur in a series. The frequency of absorption in this series varies with the type of ligand bonded to the metal ion. Ligands that cause large crystal field splits give rise to strong-field ligands, while ligands that cause small crystal field splits give rise to weak-field ligands. Thus, the order of ligands in the spectrochemical series is as follows:

Cl– < F– < H2O < NH3 < H2NC2H4NH2

The octahedral complex with the weakest field ligand will absorb light with the lowest energy and will exhibit a lower frequency d-d transition.- The octahedral titanium (III) complex having d-d electronic transition at the shortest wavelength among the given octahedral complexes is [TiF6]3–.

The octahedral titanium (III) complex having d-d electronic transition at the shortest wavelength among the given octahedral complexes is [TiF6]3–

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calculate the ph of a buffer solution that is prepared by adding 2.00 g of nh4cl(s) and 2.00g of nh4oh(l) to a volumetric flask and adding enough water to make 250.0 ml of solution.

Answers

To calculate the pH of the buffer solution, we need to use the Henderson-Hasselbalch equation: pH = pKa + log([base]/[acid]).

First, we need to calculate the concentration of the acid and base in the solution. NH4Cl is the acid and NH4OH is the base. Using their respective molar masses and the amount added, we find that [NH4Cl] = 0.069 M and [NH4OH] = 0.069 M. The pKa for NH4+ is 9.24. Plugging in the values, we get pH = 9.24 + log(0.069/0.069) = 9.24. Therefore, the pH of the buffer solution is 9.24.

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of the molecules hf and hcl , which has bonds that are more polar? a. HF bm HCl

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The molecule HF (hydrogen fluoride) has bonds that are more polar than HCl (hydrochloric acid).

In HF, the hydrogen atom forms a covalent bond with the fluorine atom. Fluorine is more electronegative than hydrogen, which means it has a stronger attraction for electrons. As a result, the electrons in the HF molecule are pulled closer to the fluorine atom, creating a partial negative charge (δ-) on fluorine and a partial positive charge (δ+) on hydrogen. This unequal sharing of electrons leads to a polar covalent bond in HF.

In HCl, the hydrogen atom forms a covalent bond with the chlorine atom. Chlorine is also electronegative, but less so than fluorine. The electronegativity difference between hydrogen and chlorine is smaller compared to hydrogen and fluorine. Consequently, the polarity of the H-Cl bond is not as strong as the polarity of the H-F bond in HF.

Therefore, HF has bonds that are more polar than HCl.

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What is the mass of water required to prepare 50.0 g of 10.0% sodium nitrate solution? A) 5.00 g B) 5.56 g C) 45.09 D) 55.6 g E) 450 g

Answers

To find the mass of water required to prepare a 10.0% sodium nitrate solution with 50.0 g of sodium nitrate, we need to first calculate the mass of sodium nitrate in the solution. The answer is C) 45.09 (rounded to two decimal places).
10.0% of 50.0 g = 5.00 g of sodium nitrate.
50.0 g + x g = total mass
Solving for x:
x g = total mass - 50.0 g
We know that the 10.0% sodium nitrate solution contains 5.00 g of sodium nitrate, so: total mass = 5.00 g sodium nitrate + x g water.  
x g = (5.00 g sodium nitrate + x g water) - 50.0 g
x g = 5.00 g sodium nitrate - 50.0 g + x g water
x g - x g water = 5.00 g sodium nitrate - 50.0 g
x g water = 50.0 g - 5.00 g sodium nitrate
x g water = 45.0 g
Therefore, the mass of water required to prepare 50.0 g of 10.0% sodium nitrate solution is 45.0 g.

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the equilibrium constant for a base ionization reaction is called the: select the correct answer below: a. base equilibrium constant
b. base ionization constant c. basicity index d. none of the above

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The equilibrium constant for a base ionization reaction is called the base ionization constant. This corresponds to option b.

The base ionization constant, also known as the acid dissociation constant (Ka) for bases, is a quantitative measure of the extent to which a base dissociates or ionizes in water.

It represents the ratio of the concentrations of the products to the concentrations of the reactants at equilibrium for the ionization reaction of a base.

The base ionization constant is denoted as Kb, and it is specific to the particular base being considered. It helps determine the strength of a base and provides valuable information about its behavior in aqueous solutions. By comparing the values of Kb for different bases, their relative strengths and reactivity can be assessed.

Options a, c, and d are incorrect because they do not accurately represent the term commonly used for the equilibrium constant of a base ionization reaction. Therefore, the correct option is B.

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find the pOH for the following:
A 1.34 x 10^-4 M solution oh hydrochloride acid

Answers

The pOH of a 1.34 x 10^-4 M hydrochloric acid solution is approximately 3.87.

To find the pOH of a hydrochloric acid (HCl) solution with a concentration of 1.34 x 10^-4 M, we need to use the equation that relates pOH to the concentration of hydroxide ions (OH-) in the solution.

Since hydrochloric acid is a strong acid, it completely dissociates in water, resulting in the formation of H+ ions. The concentration of hydroxide ions (OH-) in the solution can be considered negligible compared to the concentration of H+ ions.

The pOH is defined as the negative logarithm (base 10) of the hydroxide ion concentration:

pOH = -log[OH-]

Since [OH-] is negligible, we can assume it to be approximately equal to zero, and taking the logarithm of zero is not possible. Therefore, in this case, we can assume that the solution is acidic and that [H+] is equal to the concentration of the hydrochloric acid.

So, the pOH can be calculated as:

pOH = -log[H+]

Now, we need to determine the value of [H+] using the concentration of hydrochloric acid given, which is 1.34 x 10^-4 M.

[H+] = 1.34 x 10^-4 M

Taking the negative logarithm:

pOH = -log(1.34 x 10^-4)

Using a calculator or logarithm table, we can find the logarithm of the concentration:

pOH ≈ -(-3.87)

pOH ≈ 3.87

Therefore, the pOH of a 1.34 x 10^-4 M hydrochloric acid solution is approximately 3.87.

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why are organic molecules so diverse compared to inorganic molecules

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Organic molecules are more diverse compared to inorganic molecules due to the unique properties of carbon, its ability to form covalent bonds with other elements, and the presence of functional groups, allowing for a wide range of molecular structures and chemical reactions.

Organic molecules are primarily composed of carbon atoms, which possess a unique ability to form strong covalent bonds with other atoms, including carbon itself. Carbon atoms can bond with up to four other atoms, enabling the formation of complex and varied molecular structures. This property, known as catenation, allows carbon to form long chains, branched structures, and ring systems, resulting in an immense diversity of organic compounds.

Furthermore, carbon atoms can also bond with other elements such as hydrogen, oxygen, nitrogen, sulfur, and phosphorus, forming functional groups. These functional groups significantly influence the chemical behavior and reactivity of organic molecules. They introduce specific characteristics and properties, such as acidity, basicity, polarity, and the ability to undergo various types of reactions. The presence of functional groups further expands the possibilities for molecular diversity in organic compounds.

In contrast, inorganic molecules typically lack the same level of structural complexity and diversity found in organic molecules. While inorganic compounds can exhibit a range of chemical properties and reactions, they are often limited by the nature of their bonding and the types of elements involved. Inorganic molecules predominantly involve ionic bonding, where electrons are transferred between atoms, resulting in simpler and more repetitive structures

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