Pure acetic acid is often called glacial acetic acid because it is purified by fractional freezing at its melting point of 16.6 °C. At 1 atm, a flask containing several moles of acetic acid at 16.6 °C is briefly lowered into an infinitely large ice-water bath. When it is removed it is found that exactly 1 mol of acetic acid has frozen. Given: ΔH_fusion,acetic acid = 11.45kJ/mol and ΔH_fusion, H2O= 6.01 kJ/mol.

Required:
a. What is the change in entropy of the acetic acid?
b. What is the change in entropy of the water bath?
c. Now consider that the water bath and acetic acid are the same system. What is the entropy change for the combined system? Is the process reversible or irreversible? Why?

Answers

Answer 1

Answer:

Explanation:

a ) ΔH_fusion of acetic acid is 11.45 kJ / mol . It means 11.45 kJ of heat will be released when 1 mole of acetic acid will  freeze . During this process temperature of acetic acid will be constant .

Temperature of acetic acid  T = 16.6⁰C = 273 + 16.6 K = 289.6 K .

By definition change in entropy

ΔS = dQ / T

= dH / T

As temperature remains constant during withdrawal of heat

ΔS = ΔH / T

T = 289.6 K .

ΔH = - 11.45kJ

ΔS = - 11.45kJ / 289.6

= - 11450 / 289.6

= - 39.53 J

It will be negative as heat is released by acetic acid .

b )

Heat amounting ΔH will be absorbed by water bath so its entropy will be increased . As water bath is very large , temperature of bath also will remain constant at 289.6 K .

Increase in entropy of water bath =

ΔS = ΔH / T

T = 289.6 K .

ΔH =  11.45kJ

ΔS =  11.45kJ / 289.6

=  11450 / 289.6

=  39.53 J

c )

consider that the water bath and acetic acid are the same system : --

Total change in the heat content of the system

= 289.6 - 289.6 = 0

So for the whole system

ΔQ =ΔH = 0

Change in entropy is zero .

Δ G = ΔH - TΔS

= ΔH - ΔH = 0

ΔG = 0

Change in entropy is zero .


Related Questions

Consider a disubstituted aromatic compound. The parent name is benzene and there is a chloro and bromo substituent. Disubstituted benzenes can be described using the terms ortho, meta and para, depending on their relative distance from each other. The terms are often just abbreviated as o, m and p. In addition, the IUPAC name can use locant numbers instead of the descriptor. Br
Select the correct names for the structure.
1. 1-bromo-3-chlorobenzene
2. 3-bromo-1-chlorobenzene
3. meta-bromochlorobenzene
4. o-bromochlorobenzene
5. ortho-bromochlorobenzene
6. m-bromochlorobenzene

Answers

Answer:The correct names for the structure are:

--> 1. 1-bromo-3-chlorobenzene.

--> 3. meta-bromochlorobenzene.

--> 6. m-bromochlorobenzene.

Explanation:

Benzene is the simplest member of the aromatic hydrocarbons. It has a ring structure consisting of six carbon and six hydrogen atoms. This equally means that a benzene can have up to six substituents. One of the chemical properties is that benzene and other members of its series undergo substitution reaction whereby one or more of its six hydrogen atoms is replaced by monoatomic reagents.

Disubstituted benzene consists of two substituents which are described based on either numerical locants or specific words for the three possible forms.

The numerical locant method are used the same naming substitutes of other hydrocarbons. From the question, the numerical locant method was derived through using the following steps:

--> the functional group is benzene

--> there are two substituents which includes bromine( written as bromo) and chlorine ( written as chloro)

--> while placing the number, it's done alphabetically ('1-bromo' comes before '3-chloro') in a clockwise manner. This is to give chorine the lowest locant number.

The second naming method for a disubstituted benzene is the the ortho-, meta-, para- (or their singel letter equivalent) nomenclature method. This is only used for benzene structures.

--> ortho or O : this is used when the substituents are close to each other in the benzene ring.

--> meta or (m) : This is used when the substituents are separated by one carbon in the benzene ring.

--> para or (p): This is used when the substituents are across each other in the benzene ring

From the question, the bromine substituent is separated from the chlorine by one carbon atom, therefore it's meta-bromochlorobenzene or m-bromochlorobenzene.

A 5 mL sample of an unknown liquid is placed into a 250 mL flask that has had all of the air removed. The pressure measured in the flask is found to be 34.5kPa. In a seperate trial the student puts 214 mL of the same liquid into the same flask at the same conditions. What will the pressure measure (in kPa) in the second trial

Answers

Answer:

See explanation below

Explanation:

In this case, we can use the Boyle's law. Assuming that the temperature of both trial remains constant, then:

P₁V₁ = P₂V₂    (1)

You should note that this expression is usable when you are dealing with gases. However, we can treat this unknown liquid as a gas, because all the air on the flask is removed, and we can assume that the liquid can behave like an ideal gas.

So using the above expression, we can solve for P₂:

P₂ = P₁V₁ / V₂    (2)

In this case, we already have the values of presures and volume, so replacing in this expression:

P₂ = 34.5 * 5 / 214

P₂ = 0.806 kPa

This should be the pressure of the liquid.

Hope this helps

Which climate is a subcategory of polar climate

A ice cap
B subarctic
C highlands
D humid continental

Answers

Answer:

Ice cap

Explanation:

See its polar so like north pole and north pole is ice cap.

Answer:

Ice cap

Explanation:

Starting in the mouth, food follows a pathway through the digestive system. Describe how the mouth is involved in both mechanical and chemical digestion. (At least one paragraph)

Answers

Answer:

The mouth uses both mechanical and chemical digestion. Mechanical digestion involves physically breaking down the food into smaller pieces (using the jaw/teeth). However, chemical digestion then takes over and starts breaking down the food into simpler nutrients that can be used by the cells using saliva, which is naturally made within the mouth.

Hope this helps you! Have a great day! :D

If you were to burn a candle inside of a closed jar and the mass of the
closed jar and candle was 50 grams to begin with, what would the mass of
the jar and smoke be after the candle is done burning?

Answers

Answer:

50g

Explanation:

At the end of the burning process, the mass of the jar and smoke should be 50g after the candle burning is done.

In most systems, the law of conservation of matter finds expression. According to this law "matter is neither created nor destroyed but atoms are rearranged".

In this kind of system, no matter is allowed to escaped and the starting mass of the reactants compared to that of the product will be the same.

Would you consider an aquifer a renewable resource? Why or why not?

Answers

Answer:

an aquifer is a renewable resource

Explanation:

Aquifers are defined as the groundwater found deep in the layers of rocks.

An aquifer is considered as a renewable resource because groundwater is renewed over time. Aquifers are water resources and follow hydrological cycle through which it can renew itself.

Some of the deep aquifers are considered as  nonrenewable resource because it toll hundreds of years to accumulate.

Hence, the correct answer is yes an aquifer is a renewable resource except some deep aquifers.

Don’t skip please!!! I need help

Answers

Further explanation

Given

Atomic symbol

Required

Atomic composition

Solution

Atomic number = number of protons = number of electrons

Mass Number (A) is the sum of protons and neutrons

Number of protons and Number of Neutrons  in nucleus

Number of electrons in the shell

From the picture:

protons = 3

neutrons = 4

electrons = 3

atomic number = protons = electrons = 3

mass number = protons + neutrons = 3+4 = 7

Predict whether each of the following ionic compounds is soluble in water: a.) LiCl d.) K2 ____________________ ____________________ b.) AgCl c.) BaCO3 ____________________ e.) Fe(NO3 ____________________ )3 ____________________ O

Answers

Answer:

See answer below

Explanation:

a.) Lithium Chloride, LiCl is soluble in water.

b.) Silver Chloride, AgCl is insoluble in water.

c.) Barium Carbonate, BaCO3 is insoluble in water.

d.)Potassium, K2 is soluble in water.

e.) Iron (III) Nitrate Fe(NO3)3 is soluble in water.

All nitrates (NO3) are soluble in water.Alkali metals are soluble in water.Chlorides are soluble in water with the exception of AgCl and a few others.Carbonates are generally insoluble in water.

Why is one side of the moon called "the dark side of the moon"?

Answers

Answer:

Option C

Explanation:

The answer is option C or "The amount of time it takes to rotate around it's axis is the same amount of time it takes to revolve around Earth."Remember that the Earth and the Moons amount of time to make a full rotation is almost in sync and they're two sides of the moon, one side we do not see and that's because that side is currently faced away from the Earth which is called the dark side of the moon. Each side has two weeks oh night, and two weeks of day because of how long it takes the moon to revolve, so while we have a side towards the Earth which is illuminated by the sun we have another pointing away in the dark.

Hope this helps.

List 5 things that were made possible because of the use of microscope​

Answers

Answer:

the invention of the microscope has made seeing bacteria/cells, examining forensic evidence (such as fingerprints), studying atomic structure, tissue analysis, and the study of our ecosystem possible to the naked eye

Explanation:

hope this helps

allowed us to see bacteria, cells, things too small for a humans eye, x-rays, infrared rays, being able to see smaller and smaller structures

Help pls!!!!!!!!!!!!!!!!!!!!!!!!!

Answers

Chief Keef - Love Sosa

6:C
7:B
8:A
Hope this helps

What are essential elements in plants?​

Answers

Answer:

Chlorophyll is one. I can't quite remember other

what Li(s) + O2(g) -> Li2O(s) balanced is

Answers

Answer:

4 1 2

Explanation:

4 Li(s) + 1 O2(g) -> 2 Li2O(s)

To calculate the atoms of an element in a given molecule, we need to multiply stoichiometry by the number that is written on the foot of that element. Therefore, the balanced equation is 4 Li(s) + 1 O[tex]_2[/tex](g) [tex]\rightarrow[/tex] 2 Li[tex]_2[/tex]O(s).

What is Balanced equation?

Balanced equation is the one in which the total number of atoms of a species on reactant side is equal to the total number of atoms on product side. The mass of the overall reaction should be conserved. There are so many types of chemical reaction reaction like combination reaction, displacement reaction.

The other characteristic of balanced reaction is that physical state should be written with each compound or molecule on reactant and product side. Physical state should be written in brackets. s means solid, l means liquid, g means gas. The balanced equation for the given reaction is 4 Li(s) + 1 O[tex]_2[/tex](g) [tex]\rightarrow[/tex] 2 Li[tex]_2[/tex]O(s)

Therefore, the balanced equation is 4 Li(s) + 1 O[tex]_2[/tex](g) [tex]\rightarrow[/tex] 2 Li[tex]_2[/tex]O(s).

Learn more about the balanced equation, here:

https://brainly.com/question/7181548

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7. A mining company find a deposit of metal. Based on the other intensive properties it could be iron (7.9 g/cm), lead
(11.3 g/cmº), or nickel (8.9 g/cm.).
A 15 cm sample of it weighs 134g. Which metalis it most likely to be?

Answers

Answer:

Nickel

Explanation:

Given data:

Density of iron = 7.9 g/cm³

Density of lead = 11.3 g/cm³

Density of nickel = 8.9 g/cm³

Mass of sample = 134 g

Volume of sample = 15 cm³

Which metal it is = ?

Solution:

First of all we will calculate the density of sample and then match it with the density of given metals.

Formula:

d = m/v

by putting values,

d = 134 g/ 15 cm³

d = 8.9 g/cm³

The weighted sample is nickel metal.


Determine the the nuclei indicated in blanks in the
right side when Radium (Ra-226) undergoes an
alpha decay
Ne
226/ 88
Ra -->
+

Answers

The daughter isotope  : Radon-222 (Rn-222).

Further explanation

Given

Radium (Ra-226) undergoes an  alpha decay

Required

The daughter nuclide

Solution

Radioactivity is the process of unstable isotopes to stable isotopes by decay, by emitting certain particles,  

alpha α particles ₂He⁴ beta β ₋₁e⁰ particles gamma particles ₀γ⁰ positron particles ₁e⁰ neutron ₀n¹

The decay reaction uses the principle: the sum of the atomic number and mass number before and after decay are the same

Radium (Ra-226) : ₈₈²²⁶Ra

Alpha particles : ₂⁴He

So Radon-226 emits alpha α particles ₂He⁴  , so the atomic number decreases by 2, mass number decreases by 4

The reaction :

₈₈²²⁶Ra ⇒ ₂⁴He + ₈₆²²²Rn

Some students use an apple to represent the Earth. What is the best reason to use an apple for this comparison?

a. The skin of an apple is very thin, and the crust of the Earth very thin.

b. The flesh of an apple is made of the same material all the way through, and the interior of the Earth is the same all the way through.

c. The seeds of the apple are very light in comparison to the rest of the apple, and the core of the Earth is also made of very light matter.

d. The stem of the apple comes from the core and the North Pole comes from the Earth’s core.

Answers

C.The seeds of the apple are very light in comparison to the rest of the apple, and the core of the earth is also made of very light matter.

How are the cells made by meiosis different from the original parent cell that
produced them?

Answers

Mitosis creates two identical daughter cells that each contain the same number of chromosomes as their parent cell. In contrast, meiosis gives rise to four unique daughter cells, each of which has half the number of chromosomes as the parent cell.

Why is the liquid oxygen machine producing less liquid oxygen than normal?

Answers

Answer:

Liquid oxygen evaporates at only a slightly higher temperature than liquid nitrogen because they have similarly low attraction between molecules. This would mean less liquid oxygen is coming out of tank 3 because some of it is evaporating as a gas instead.

The liquid oxygen machine is producing less liquid oxygen than normal because there's a low attraction between the molecules.

It should be noted that oxygen in its liquid state will take up less space. It can also be stored at a lower pressure than when it's in its gaseous state.

From the complete question, the liquid oxygen evaporates at a slightly higher temperature than the liquid nitrogen. The reason for this is due to the fact that they have similarly low attraction between molecules.

Read related link on:

https://brainly.com/question/16173485

Calculate the number of grams of 02, produced when 43 grams of potassium chlorate decomposes.
2KClO3=3O2+2KCl

Answers

Mass O2 = = 16.832 g

Further explanation

Given

43 grams of potassium chlorate

Required

Mass of O2

Solution

Reaction

2KClO3 ⇒3O2 + 2KCl

Mol KClO3 :

= mass : MW

= 43 g : 122,55 g/mol

= 0.3509

From the equation, mol O2 :

= 3/2 x moles KClO3

= 3/2 x 0.3509

= 0.526

Mass O2 :

= 0.526 x 32 g/mol

= 16.832 g

What type of equation is this?
AlCl3 + NaOH → Al(OH)3 + NaCL
double
single
synthesis
decomp
combustion

Answers

Double. I guess, I’m sorry.

Disaccharides are held together by a glycosidic bond. Hydrolysis of the disaccharide requires_____

Answers

Answer:

monosaccharides and glycosidic, I think

Explanation:

Answer:

pasagottt po plss

Explanation:

edi wow

In a chemical equation, the new substance that is produced from a chemical reaction is called __________.

Answers

Answer:

products

Explanation:

yeah the answer is product

The answer is products.


A chemical reaction is the process in which atoms present in the starting substances rearrange to give new chemical combinations present in the substances formed by the reaction. These starting substances of a chemical reaction are called the reactants, and the new substances that result are called the products.

You are working to earn enough money for a vacation which costs 2100. Your take-home pay is $16.50/hour, but you only work 4-hour shifts each day. How many days will it take for you to earn enough money to pay for your vacation if all the money you earn goes towards your vacation?

Answers

Answer:

32 days.

Explanation:

First we determine how much is made in a day.

16.50 x 4 = 66.

Next, we divide 2100 by 66 to reach our amount of days needed.

2100 / 66 = 31.818181... [81 is what repeats over and over.]

We round this up to the nearest whole number. You can't underpay, so you have to round.

The next whole number would be 32, so our answer is 32 days.

How many grams are in 0.00321 mol NI

Answers

Solution

The mole is the number of particles contained in a substance

1 mol = 6.02.10²³

Moles can also be determined from the amount of substance mass and its molar mass

mol = mass : molar mass

mass = mol x molar mass

Molar mass = 58,6934 g/mol

Input the value :

mass = 0.0321 x 58,6934 g/mol

mass = 1.884 g

Acetylene gas is often used in welding torches because of the very high heat produced when it reacts with oxygen gas, producing carbon dioxide gas and water vapor. Calculate the moles of water produced by the reaction of of oxygen.

Answers

Answer:

one mole of oxygen will produce [tex]0.4[/tex] moles of water

Explanation:

The balanced chemical reaction is as follows -

2 C2H2 + 5 O2 --> 4 CO2 + 2 H2O

As we can see in this reaction

5 mole of oxygen (on the reactant side) will produce 2 mole of water (on the product side)

Hence, one mole of oxygen will produce [tex]\frac{2}{5} =0.4[/tex] moles of water

Calculate the number of moles in 15.5g of CaSO4.5H2O

Answers

Answer:

No. of moles = 0.0685

Explanation:

Given mass, m = 15.5g

We need to find the number of moles in 15.5 g of CaSO₄.5H2O

First, we find the mass of CaSO₄.5H2O.

M = (1×40)+(1×32)+(4×16)+(5×18)

M = 226 g/mol

We know that,

Number of moles = given mass/molar mass

[tex]n=\dfrac{15.5\ g}{226\ g/mol}\\\\n=0.0685\ \text{mol}[/tex]

Hence, there are 0.0685 moles in 15.5 g of CaSO₄.5H2O.

For the reaction of reducing benzil (MW 210.23 g/mol) with sodium borohydride (MW 37.83 g/mol), if 2.56 g of benzil and 0.38 g of sodium borohydride were used to make hydrobenzoin (MW 214.26 g/mol), and 2.22 g of hydrobenzoin was obtained, which chemical is limiting reagent

Answers

Answer:

NaBH₄

Explanation:

First, we need to write the chemical formula of all the compounds:

Benzil: C₁₄H₁₀O₂

Sodium Borhydride: C₁₄H₁₀O₂

Hydrobenzoin: C₁₄H₁₄O₂

Now, let's write the reaction that is taking place and write all the products:

C₁₄H₁₀O₂ + 2NaBH₄ + 2H₂O -----------> C₁₄H₁₄O₂ + 2BH₃ + 2NaOH

We can see that the reaction is already balanced, so we don't need to do anything else.

The question of this exercise is to determine the limiting reagent of the reaction, in other words, the reagent that controls the reaction and produces the 2.22 g of the hydrobenzoin. And to know this we need to see the mole ratio in both reactants, and compare them to the given moles (That can be obtained with the given masses and MW)

According to the above reaction, we have a mole ratio of 1:2, so, let's calculate the moles of benzil and the borohydride, and see which of them is the limiting reactant:

moles C₁₄H₁₀O₂ = 2.56 / 210.23 = 0.0122 moles

moles NaBH₄ = 0.38 / 37.83 = 0.01 moles

moles  C₁₄H₁₄O₂ = 2.22 / 214.26 = 0.0103 moles

We have the moles of every species, now, let's see the mole ratio

If 1 mole of C₁₄H₁₀O₂ -----------> 2 moles of NaBH₄

Then 0.0122 moles C₁₄H₁₀O₂ ----------> X moles of NaBH₄

Solving for X:

X = 0.0122 * 2 / 1 = 0.0244 moles of NaBH₄ are required.

However, we only have 0.01 moles of NaBH₄, and we need so much more of this to completely react with the moles of the benzil. Therefore we can safely assume that the limiting reagent is the NaBH₄

Another data that we can use for this, is the fact the produced moles were 0.0103, and this value is nearest to the moles of NaBH₄ rather than the moles of the benzil.

So, in conclusion, Limiting reagent NaBH₄

Hope this helps

(30 POINTS) Which order shows the levels of organization from largest to smallest?

organism, organ system, cell, organ, tissue
organism, tissue, organ system, organ, cell
organism, organ, organ system, cell, tissue
organism, organ system, organ, tissue, cell

Answers

Answer:

cell,tissue,organ,organ system,organism

Explanation: Cells becoming specialized are better able to carry out specific functions. So they work together in groups. different tissues are grouped together to form specialized organs which may perform one or more functions. Organs work together in organ systems. Systems then work together ina an organized way to form a multicellular organism.

Answer:

Which of the following would most likely be caused by a tsunami?

A. reshaping of the shoreline
B. seafloor spreading
C. island formation
D. mountain formation


ASAP please

Answers

the answer Is A hope it helps

I think it’s A but also hear me out on this, Socratic is a really good app for questions like these and you don’t have to wait for someone to answer it!

onsider the iodination of salicylamide by sodium iodide and sodium hypochlorite via an electrophilic aromatic substitution to form iodo-salicylamide. Reaction scheme illustrating the iodination of salicylamide by sodium iodide and sodium hypochlorite via an electrophilic aromatic substitution to form iodo-salicylamide. Calculate the molar masses of the reactants and product. Report molar masses to 1 decimal place.

Answers

Answer:

The answer is "[tex]\bold{263 \ and \ 137.1 \frac{g}{ mol}}[/tex]".  

Explanation:

The chemical formula for Salicylamide: [tex]C_7H_7NO_2[/tex]

[tex]\to (12.011 \ \frac{g}{mol} \times 7)+(1.008 \ \frac{g}{mol} \times 7)+(14.0067 \frac{g}{mol} \times 1)+(15.999 \frac{g}{mol} \times 2) \\\\\to (84.077 \ \frac{g}{mol} )+(7.056 \ \frac{g}{mol} )+(14.0067 \frac{g}{mol})+(31.998 \frac{g}{mol} ) \\\\\to (84.077 \ \frac{g}{mol} )+(7.056 \ \frac{g}{mol} )+(14.0067 \frac{g}{mol})+(31.998 \frac{g}{mol} ) \\\\ =137.1377 \approx 137.1\ \frac{g}{mol}[/tex]

The chemical formula of Iodosalicylamide:[tex]C_7H_6INO_2[/tex]

[tex]\to (12.011\frac{g}{mol}\times 7)+(1.008\frac{g}{mol}\times 6)+(126.904\frac{g}{mol}\times 1)+(14.0067\frac{g}{mol}\times 1)+(15.999\frac{g}{mol}\times 2) \\\\\to (84.077\frac{g}{mol})+(6.048\frac{g}{mol})+(126.904\frac{g}{mol})+(14.0067\frac{g}{mol})+(31.998\frac{g}{mol}) \\\\=263.0337 \approx 263.0\ \frac{g}{mol}[/tex]

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