Using the rules that we developed in this chapter (ARIO), we might have expected these two compounds to have the same pKa. Nevertheless, they are different. Salicylic acid is apparently more acidic than its constitutional isomer. Can you offer an explanation for this observation

Answers

Answer 1

Answer:

The correct answer is

- after deprotonation carboxylic acid stabilizes by binding -OH group with hydrogen bonding in salicylic acid and while it's not possible with its constitutional isomer (para-hydroxy benzoic acid).

The more electronegative atoms are replaced by the H atom of the carboxylic group and form more stabilize carboxylic acid which not takes place in para-hydroxy benzoic acid.


Related Questions

2C 2 H 2 (g)+5O 2 (g) CO 2 (g) + 2H 2 O (l)

Answers

Answer:

2c2gh2+5cg2o4+2h2lo

Explanation:

A buffered solution _______. Select the correct answer below: fails to keep hydronium and hydroxide ion concentrations nearly constant when strong acids or bases are added. maintains a constant or nearly constant pH when small amounts of strong acids or bases are added. acts to keep the hydroxide ion concentration nearly constant. acts to keep the hydronium ion concentration nearly constant.

Answers

I believe it is the second one

The correct option for the given question about Buffer Solution is Option B) which is maintains a constant or nearly constant pH when small amounts of strong acids or bases are added.

What is a Buffer Solution?When a little quantity of acid or base is diluted or added, the buffer solution undergoes very slight variations in its hydrogen ion concentration (pH). pH may be maintained in buffer solutions, which are mixtures of a weak acid and its conjugate base or a weak base and its conjugate acid.Acidic and alkaline buffers are the two main groups into which buffer solutions are commonly categorized.A weak acid and its salt are combined with a strong base to create an acidic buffer, which has an acidic pH.A weak base, its salt, and a strong acid are combined to create an alkaline buffer, which has a basic pH.

Thus we conclude that when weak acids or bases are supplied in small amounts, the pH remains steady or almost constant.

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How much heat is transferred when 7.19 grams of H2 reacts with excess nitrogen, according to the following equation: N2(g) + 3 H2 (g) --> 2 NH3 (g) \DeltaΔH = +46.2 kJ

Answers

Answer:

[tex]Q=54.8kJ[/tex]

Explanation:

Hello there!

In this case, according to the given chemical reaction, it is possible for us to realize that the 46.2 kJ of energy are given per mole of reaction, which are related to 3 moles of hydrogen; Thus, we can calculate the energy per mole of hydrogen as shown below:

[tex]\Delta H=\frac{46.2kJ}{mol} *\frac{1mol}{3molH_2}\\\\ \Delta H=15.4\frac{kJ}{molH_2}[/tex]

Now, to calculate the total energy, we convert the grams to moles of hydrogen as shown below:

[tex]Q=7.19gH_2*\frac{1molH_2}{2.02gmolH_2}*15.4\frac{kJ}{molH_2} \\\\Q=54.8kJ[/tex]

Best regards!

A 0.10M NH3 solution is 1.3% ionized, calculate the hydrogen ion concentration

Answers

Answer:NH3 + H2O <==> NH4+ + OH-

0.10 x 0.013 = 0.0013 M (this is the hydroxide concentration)

Kw = [H+] [H-]

1.00 x 10^-14 = (x) (0.0013)

x = 7.7 x 10^-12 M

Explanation:

arrange the following group of atoms in order of decreasing atomic size:B,Al,Ga​

Answers

Answer:

B<Ga<Al

Explanation:

Hope this helps

A scientist wants to display the numbers of gallons of fuel that were used up
in a one-hour period by three different types of motors. What type of visual
display should the scientist use?


Help please

Answers

Answer:

bar graph

Explanation:

2. Calculate the concentration (in molarity) of a NaOH solution if 25.0 mL of the solution are needed to neutralize 17.4 mL of a 0.312 M HCl solution.

Answers

Answer:

0.217 M NaOH

Explanation:

M1V1 = M2V2

M1 = 0.312 M HCl

V1 = 17.4 mL HCl

M2 = ?

V2 = 25.0 mL NaOH

Solve for M2 --> M2 = M1V1/V2

M2 = (0.312 M)(17.4 mL) / (25.0 mL) = 0.217 M NaOH

A compound containing nitrogen and oxygen is decomposed in the laboratory. It produces 24.5 g nitrogen and 70.0 g oxygen. Calculate the empirical formula of the compound.

Answers

Answer:

N2O5

Explanation:

1. Convert to moles

24.5g N * 1mol/14g = 1.75

70.0g * 1mol/16g = 4.375

2. Divide each value by the smallest

1.75/1.75 = 1

4.375/1.75 = 2.5

3. Multiply each by a whole number so that they are both whole numbers

1*2 = 2

2.5*2 = 5

4. These are moles of elements present in the compound

Answer: N2O5

Question: You decompose a compound containing nitrogen and oxygen in the laboratory and produce 24.5 g of nitrogen and 70.0 g of oxygen. Calculate the empirical formula of the compound.

if a gas sample has a pressure of 30.7 kPa at 273 K, what does the temperature have to decrease to lower the pressure to 28.4 kPa?​
253K
268K
262K

Answers

253 K

P1/T1 = P2/T2

P1 = 30.7 kPa
T1 = 273 K
P2 = 28.4 kPa

Solve for T2 —> T2 = P2T1/P1
T2 = (28.4 kPa)(273 K) / (30.7 kPa) = 253 K

If 5.32 mols N2 and 15.8 mols H2 react together, what mass NH3 can be
produced? Which is the limiting reactant?

Answers

Answer:

2.87 gram

N2 is the limiting agent

Explanation:

We will find out if there is sufficient N2 and h2 to produce NH3

a) For 2.36 grams of N2

Molar mass of N2 = 28.02

Number of moles of N2 in 2.36 grams = 2.36/28.02

Mass of NH3 = 17.034 g

Now NH3 produced form 2.36 grams of N2 =  

2.36/28.02 * 2 * 17.034 = 2.87 g NH3

b) For 1.52 g of H2  

NH3 produced = 1.52/2.016 * (2/3) * 17.034 = 8.56

N2 Is not enough to produce 2.87 g of NH3 and also H2 is not enough to make 8.56 g of NH3.  

N2 is the limiting agent as it has smaller product mass

Calculate the moles of argon gas at STP in 33 L. Round answer to 2 significant figures.

Answers

Answer:

1.5 mol

Explanation:

Step 1: Given data

Volume of argon gas: 33 LStandard temperature: 273.15 KStandard pressure: 1 atm

Step 2: Calculate the moles corresponding to 33 L of argon at standard temperature and pressure (STP)

At STP, 1 mole of argon gas occupies 22.4 L.

33 L × 1 mol/22.4 L = 1.5 mol

Bases are typically found in

Answers

Answer:

they are typically found in

1)soap

2) detergent

3) baking soda etc..

Nitrous oxide (N2O), more commonly known as laughing gas, is used as a mild sedatitive during various dental procedures.As a gas, it has a densityof 1.977 x 10-3g/mL.Wheniron is exposed to oxygen it forms rust (Fe2O3), which is a solid and has a density value of 5.25 g/mL.Why are the density values so different among these substances?
a)The metal atoms weigh more than the atoms of the gas.
b)The metal forms metallic bonds which are more greatly affected by gravity, increasing the mass.
c)The metal is a solid, and solids weigh more based on the principles of their states of matter.
d)There are fewer gas particles than solid particles in the same volume.

Answers

Answer:

B.

Explanation:

The metal forms metallic bonds which are more greatly affected by gravity, increasing the mass.

For any molecule at the surface the resulting surrounding forces equal zero
True
False
????????????????????????????????????????????????????,,

Answers

False is the correct answer
I think it’s true
Hope it is!

Reaction of Nitrile with Grignard Grignard reagents react with nitriles to give an intermediate imine anion that is hydrolyzed by the addition of water to yield a ketone. The mechanism is similar to the reduction of a nitrile to an amine except that only one nucleophilic addition occurs instead of two, and the nucleophile is a carbanion rather than a hydride ion.

Required:
Draw curved arrows to show the movement of electrons. in this step of the mechanism. Arrow-pushing Instructions

Answers

Answer:

its a.

Explanation:

how many mg are in 125ml of
phosphoric acid?

Answers

Answer:

125000mg

Explanation:

1ml = 1000mg

125(1000) = 125000mg

Which of the following methods of fossil formation is formed in dry areas due to a lack of moisture?

a
Mummification
b
Casts and molds
c
Amber fossil
d
Carbonization

Answers

I don’t know the answer but my guess would be mummification

The methods of fossil formation in dry areas due to a lack of moisture is mummification. The correct option is a.

What is mummification?

Mummification is the process of deliberately drying or embalming flesh to preserve the body after death.

This typically entailed removing moisture from a deceased body and desiccating the flesh and organs with chemicals or natural preservatives such as resin.

Mummification served the purpose of keeping the body intact so that it could be transported to a spiritual afterlife.

The body was stripped, positioned on a slanted table, and washed in natron solution (a naturally occurring salt used both as soap and a preservative).

The brain was extracted from the skull through a hole in the ethmoid bone (the bone separating the nasal cavity from the skull cavity).

Thus, the correct option is A.

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How many molecules of CO2 are there in 3.55 g of CO2?

Answers

Answer:

4.9∗1022  molecules of CO2 in a 3.6 gram sample.

Explanation:

The gram molecular weight of co2 is 44 gms.

So the number of molecules in 44 gms of co2 is 6.023×10^23 .

Then the number of molecules in 3.6 gms of co2 is (6.023×10^23×3.6)÷44 = 4.92×10^22

In a given compound, the mass of sulfur (S) is 40.05 g and the mass of oxygen (O) is 59.95 g. What is
the empirical formula of the compound

Answers

Answer:

[tex]SO_3[/tex]

Explanation:

Hello there!

In this case, according to the definition of the empirical formula as the smallest representation of the molecular formula of a chemical compound; for us to determine it, we first need to calculate the moles of sulfur in 40.05 g and those of oxygen in 59.95 g as shown below:

[tex]n_S=\frac{40.05g}{32.07g/mol}= 1.25molS\\\\n_O=\frac{59.95g}{16.00g/mol}=3.75molO[/tex]

Now, we perform the following mole ratios to figure out the subscripts in the empirical formula, by dividing over the fewest number of moles:

[tex]S=\frac{1.25}{1.25}=1 \\\\O=\frac{3.75}{1.25}=3[/tex]

Therefore, the empirical formula turns out:

[tex]SO_3[/tex]

Best regards!

The solubility of a solid in a liquid generally increases with increase temperature.

True
Or
False

Answers

Answer:

False, Solubility increases with temperature for most solids.

Explanation:


15. Kinetic and potential energy both relate to
a. friction
a. heat
b. light
d. motion

Answers

Answer:

All forms of energy are either potential or kinetic energy. Potential refers to stored energy while kinetic is energy in motion.

Explanation:

hope help you pls thanks...

D is correct option

D, Motion

All forms of energy are either potential or kinetic energy. Potential refers to stored energy while kinetic is energy in motion.

Which of the following sentences describe how latitude affects a biome? (There may be more than one answer).

Question 4 options:

In the far north, the summers are too short and cold for trees.


As you travel east, the climate gets colder.


The closer the area is near to the equator, the hotter the weather.


The higher in elevation, the colder the environment.

Answers

Answer:

A and C

Explanation:

The other answers didn't seem reasonable,

I took the quiz and got it right.

If I am wrong, please correct me

The biome can be given as the collection of flora and fauna in the region. The latitude affects the biome, with the short summers in the north and hot weather at the equator.

What is latitude?

The latitude can be given as the horizontal lines imaginary drawn on the earth. The equator is the center of latitude passing from the middle of the earth.

The sun's rays fall directly towards the equator, while the poles in the north and the south experiences the transverse rays of the sun.

The direct rays falling at the equator termed the area closer to the equator warmer, while the falling rays to the north resulted in the short summers and cold for trees. Thus, options A and C are correct.

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At some temperature for the equilibrium PX3(g) + X2(g) # PX5(g) the equilibrium constant is 0.74. At the same temperature the equilibrium constant for PX5(9) + PX3(g) X2(g) is​

Answers

Answer: The equilibrium constant for [tex]PX_5(g)\rightarrow PX_3(g)+X_2(g)[/tex] is 1.35

Explanation:

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as [tex]K_c[/tex]  

For the given chemical reaction:

[tex]PX_3(g)+X_2(g)\rightarrow PX_5(g)[/tex]

The expression for [tex]K_c[/tex] is written as:

[tex]K_c=\frac{[PX_5]^1}{[PX_3]^1[X_2]^1}[/tex]

[tex]0.74=\frac{[PX_5]^1}{[PX_3]^1[X_2]^1}[/tex]

For the reverse chemical reaction:

[tex]PX_5(g)\rightarrow PX_3(g)+X_2(g)[/tex]

The expression for [tex]K_c'[/tex] is written as:

[tex]K_c'=\frac{[PX_3]^1[X_2]^1}{[PX_5]^1}[/tex]

[tex]K_c'=\frac{1}{K_c}=\frac{1}{0.74}=1.35[/tex]

The equilibrium constant for [tex]PX_5(g)\rightarrow PX_3(g)+X_2(g)[/tex] is 1.35

arrange
these liquids in order of increasing surface tension: water,
hexane, ethanol.

Answers

The magnitude of surface tension of liquid depends on the attractive forces between the molecules. Arrange the following in increasing order of surface tension:

water, alcohol (C2H5OH) and hexane [CH3(CH2)4CH3)].  

Answer:

Hexane, Methanol, Water

Explanation:

I did the assessment

Several elements must be transmuted to sea the real implications of this event
a.surpassed
b.estimated
c.changed
d.summed

thanks guys :)​

Answers

C, Changed because it’s transmuted which can cause change of events

what volume of 1.75 h2so4 would be needed to neutralize 350 ml of 3.33 m sodium hydroxide?​

Answers

Answer:

1.332 L

Explanation:

The reaction that takes place is:

H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O

First we calculate the number of NaOH moles, using the given volume and concentration:

350 mL * 3.33 M = 1165.5 mmol NaOH

Then we convert NaOH moles into H₂SO₄ moles, using the stoichiometric coefficients:

1165.5 mmol NaOH * [tex]\frac{2mmolH_2SO_4}{1mmolNaOH}[/tex] = 2331 mmol H₂SO₄

Finally we calculate the required volume of a 1.75 M solution of H₂SO₄, using the concentration and number of moles:

2331 mmol / 1.75 M = 1332 mL

We can convert mL into L:

1332 mL / 1000 = 1.332 L

Titrations provide a method of quantitatively measuring the concentration of an unknown solution.

a. Trueb. False

Answers

Answer: True

Explanation:

Titration is a quantitative technique where a solution of known concentration is used to determine the concentration of an unknown solution. The titrant (the known solution) is added from a burette to a known quantity of the the unknown solution until the reaction is complete.

By knowing the volume of titrant,  we can determine the concentration of the unknown.

Thus the statement Titrations provide a method of quantitatively measuring the concentration of an unknown solution is True .

Lipids include:
A. fats and water
B. Oils and carbohydrates
C. Waxes and sterols

Answers

I’m pretty sure it’s A

Answer: C

waxes and sterols

Explanation:

edge 2021

How many grams are in 3.5 moles of H2O?

Answers

Answer:

Hi

Explanation:

We assume you are converting between moles H2O and gram. You can view more details on each measurement unit: molecular weight of H2O or grams This compound is also known as Water or Dihydrogen Monoxide. The SI base unit for amount of substance is the mole. 1 mole is equal to 1 moles H2O, or 18.01528 grams.

1 mole is equal to 6.023 × 10 ²³ molecules. 63 grams  are in 3.5 moles of H2O.

What do you mean by mole ?

The term mole is defined as the amount of substance of a system which contains as many elementary entities.

One mole of any substance is equal to 6.023 × 10²³ units of that substance such as atoms, molecules, or ions. The number 6.023 × 10²³ is called as Avogadro's number or Avogadro's constant.

The mole concept can be used to convert between mass and number of particles.

We expect you are converting between moles H2O and gram. The molecular weight of H2O or gram's This compound is also known as Water or Dihydrogen Monoxide. The SI base unit for amount of substance is the mole. 1 mole is equal to 1 moles H2O, or 18.01528 grams.

Thus, 63 grams  are in 3.5 moles of H2O.

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How many moles of magnesium nitrate are produced when he reacts 0.34 moles of nitric acid with excess magnesium?

Answers

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