Write a mechanism for the conversion of the aldol addition product, 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone, to the aldol condensation product, (E)-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propenone. Be as complete as possible and show electron flow for all steps.

Answers

Answer 1

Solution :

"Aldol" stands for the abbreviation, aldehyde and alcohol. When a ketone or an aldehyde's enolate reacts with the carbonyl of a  molecule at the alpha carbon, under the acidic or basic conditions so as to obtained the ketone or β-hydroxy aldehyde, is known as an aldol reaction.

For the conversion of the aldol addition product of a 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone to an aldol condensation product of (E)-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propenone, the mechanism is given in the diagram a below :

Write A Mechanism For The Conversion Of The Aldol Addition Product, 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone,

Related Questions

Calculate the percent composition of C in carbon dioxide.

Answers

Answer:

27.27%

Explanation:

answer is 27.3%
have a good day!

Arrange the following substance into acid,base and neutral. sodium chloride, tomato juice, vinegar,sea water,bicorbonate of sodium​

Answers

Answer:

sodium chloride: neutral.

tomato juice: acid.

vinegar: acid.

sea water: base.

bicarbonate of sodium​: base.

Explanation:

Hello there!

In this case, in agreement to the definition of the pH, as the measure of the acidity and basicity of a substance; it is important to recall that pH's below 7 stand for acidic substances and pH's above 7 stand for basic substances, whereas a pH of 7 defines a neutral one. In such a way, given the pH's of the given substances, 7, 4.05 to 4.65, around 2.5, about 8.1 and about 8.3 respectively for sodium chloride, tomato juice, vinegar, sea water, bicarbonate of sodium​, it is possible to assert:

sodium chloride: neutral.

tomato juice: acid.

vinegar: acid.

sea water: base.

bicarbonate of sodium​: base.

Best regards!

all metals rust please answer false or true​

Answers

Answer:

True

Explanation:

All metals do rust but at different rates. Gold, platinum, and silver can rust if but at different rates. It can take time for it to rust, if you clean your metals, it won't rust, it'll take awhile before it rusts if you keep cleaning them.

Hopefully this helps :3 sorry if wrong :( plz mark brainiest if correct :D your bootiful/handsome! Have a great day luv <3

-Bee~

What will be the pH of a buffer solution containing an acid of pKa7.5, with an acid concentration exactly one fourth of that of the conjugate base

Answers

Answer: pH of buffer solution is 8.1

Explanation:

The formula for the Henderson–Hasselbalch equation is:

[tex]pH=pK_a+\log\frac{[A^-]}{[HA]}[/tex]

[tex]pH[/tex] is the concentration of [tex][H^+][/tex]

[tex]pK_a[/tex] is the acid dissociation constant,

[tex]A^-[/tex] and [tex]HA[/tex] are concentrations of the conjugate base and starting acid.

Putting in the values we get:

[tex]pH=7.5+\log\frac{x}{\frac{x}{4}}[/tex]

[tex]pH=8.1[/tex]

Thus pH of buffer solution is 8.1

Research and describe one career in health and fitness that you would consider

Answers

i would research the job of being a fitness coach, that is very popular in health and fitness

Answer:

a PE teacher would be in both catagories  of heath and fitness

Explanation:

The formula for chromium (vi)bromate

Answers

Answer: The formula of chromium fluoride is CFr2.

A substance that contains two or more kinds of atoms is

Answers

A substance that contains two or more kinds of atoms is a molecule.

Which of the following best describes the type of particle found in the cloud around an atom’s nucleus?
It has a negative charge and much less mass than a neutron
It has a negative charge and about the same mass as a neutron.
It has a negative charge and about the same mass as a neutron.
It has a positive charge and about the same mass as a neutron.

Answers

The second one is the best to go with


8. If 134 L of Nitrogen gas at STP is combined with 99 L of Chlorine gas at STP,
Which is the limiting reactant?
N2 + Cl2 → NCI3
.

Answers

Answer:

Cl₂ is the limiting reactant.

Explanation:

We'll begin by writing the balanced equation for the reaction. This is illustrated below:

N₂ + 3Cl₂ —> 2NCl₃

From the balanced equation above,

1 L of N₂ reacted with 3 L of Cl₂.

Finally, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

1 L of N₂ reacted with 3 L of Cl₂.

Therefore, 134 L of N₂ will react with = 134 × 3 = 402 L of Cl₂.

From the calculation made above, we can see that a higher volume (i.e 402 L) of Cl₂ than what was given (i.e 99 L) is needed to react completely with 134 L of N₂.

Therefore, Cl₂ is the limiting reactant and N₂ is the excess reactant.

Determine the amount of current going through a 50ohms; resistor with a voltage of 120 v

Answers

Answer:

98.356 ohms is the answer

HELP ASAP PLEASE!!! :)

Answers

Answer:

Alkane

Explanation:

Alkenes have CH in their condensed formulas and alkynes have C in their condensed formulas. There are only CH3 and CH2 so it's an alkane.

Consider a solution which is 0.10M in NH3 and 0.20M in NH4Cl. Choose ALL of the following that are false. If a small amount of NaOH is added, the pH becomes slightly more basic. If HCl is added, the H ions react with the NH3. If a small amount of HCl is added, the pH becomes slightly more basic. If NaOH is added, the OH- ions react with the NH3. If NH4NO3 is added, the pH becomes more basic.

Answers

Answer:

The incorrect or the false options are -

(B) - If NH4NO3 is added, the pH becomes more basic.

(D) - If a small amount of HCl is added, the pH becomes slightly more basic.

 (E) - If NaOH is added, the OH- ions react with the [tex]NH_3[/tex].

Explanation:

The given solution the buffer basic .

When a small amount of either is added, the hydrogen ion reacts with the ammonium ion, raising the pH slightly.When a small amount of HCl is added, the hydronium ion reacts with the ammonia, raising the pH slightly.

Therefore , the options A ( If a small amount of NaOH is added, the pH becomes slightly more basic.) and C ( If HCl is added, the H+ ions react with the NH3.) All other B , D , E are false .

Good Morning I have a question I need help and can not find the answer o it maybe someone help me? The question is _______ Most Of the Energy that drives water cycle comes from__________? (this is from Science)

Answers

Answer:

hydro, water

Explanation:

Which salt preparation uses a burette and a pipette

Answers

potassium chloride from potassium hydroxide and hydrochloric acid

8. How much heat will be released when
18.6 g of hydrogen reacts with excess O2
according to the following equation?

Answers

Answer:

15 is it

Explanation:

Question 7 point
What is the name of the covalent compound with the formula P2N3?

Answers

List of covalent compounds
Binary molecular (covalent) compounds
compound systematic name
NO2 nitrogen dioxide
N2O3 dinitrogen trioxide
N2O4 dinitrogen tetroxide
N2O5 dinitrogen pentoxide

2 Nal + Pb(NO3)2
2 NaNO3 + Pb12
How many oxygen atoms are on the left side of the equation?

Answers

there are 6 O atoms suvdjwndje

Why are some resources, like fossils, found in some places and not in others?

Answers

Answer:

Because thats where the animal passed away

Explanation:

when 70.0 grams of mno2 reacted with 128.0 grams of hcl, the reaction resulted in a 62.7% yield of chlorine gas. what is the actual yield of chlorine gas in grams? Mno2 + HCI —> MnCl2 + h2o + cl2​

Answers

Answer:

35.8g of Cl₂ is the yield

Explanation:

Based on the reaction:

MnO₂ + 4HCl → MnCl₂ + 2H₂O + Cl₂

1 mole of MnO₂ and 4 moles of HCl react producing 1 mole of Cl₂

To solve this question we must find limiting reactant. with limiting reactant we can find the theoretical yield of Cl₂. As the actual yield is the 62.7% we can find actual yield of Cl₂ in grams:

Moles MnO₂ -Molar mass: 86.9368g/mol-:

70.0g * (1mol / 86.9368g) = 0.805 moles

Moles HCl -Molar mass: 36.46g/mol-:

128.0g * (1mol / 36.46g) = 3.51 moles

For a complete reaction of 3.51 moles of HCl are required:

3.51 moles HCl * (1mol MnO₂ / 4mol HCl) = 0.878 moles MnO₂.

As there are just 0.805 moles of MnO₂, MnO₂ is limiting reactant.

1 mole of MnO₂ produce 1 mole of Cl₂. The theoretical moles of Cl₂ produced are 0.805 moles.

As the yield is of 62.7%, the yield of Cl₂ is:

0.805 moles * (62.7 / 100) = 0.505 moles Cl₂. In grams:

0.505 moles Cl₂ * (70.906g / mol) =

35.8g of Cl₂ is the yield

How much energy ( in joule ) does the Sun emit in one day (24 hours)? I've previously answered with 3.32, but it was incorrect. Please help thanks.

Answers

It is about 3.86 which is 10⁶⁶ watts

Answer:

410 quintillion Joules or 430,000,000,000,000,000,000 Joules

6. (5 pts) From among the isomeric compounds with molecular formula C4H9Cl, identify the one having a 1H NMR spectrum that: a) contains only a single peak b) has several peaks, including a doublet at d 3.4 c) has several peaks, including a triplet at d 3.5 d) Has several peaks, including two distinct signals, each with an integration of 3H, one of them a triplet at d 1.0 and the other a doublet at d 1.5.

Answers

Answer:

Explanation:

Chemically identical protons in 1HNMR spectra are protons that are found in the same chemical system and produce one signal in the spectra. Non-equivalent protons are protons that reside in various chemical environments and display different signals.

(a) The provided alkyl halide has four carbons, nine hydrogens, and one chlorine atom, according to the molecular formula. To achieve a single NMR peak, all protons (9 hydrogens) must be in the same chemical environment. That is, the carbon skeleton should be made up of three methyl groups, each bound to a single carbon atom.

As a consequence, the tert-butyl chloride structure can be present. That it has three methyl groups that are all the same and are all bound to the same carbon atom. As a result. A single peak is generated by proton NMR.

(b) The other isomeric variant of C4H9Cl, which has several peaks and a doublet at d3.4, could have a proton at a nearby carbon. And then does it produce a doublet. To create the doublet, two methyl groups should be substituted for the carbon. The value of 3.4 indicates that the protons can be exposed to chlorine. As a result, the compound's composition is iso-butyl chloride.

(c) The compound C4H9Cl can have two protons on adjacent carbons since it has multiple peaks and a triplet at d3,5. And then does it generate a triplet. The meaning of 3.5 indicates that the protons should be exposed to chlorine. As a result, the compound's composition is n-butyl chloride.

(d) The compound C4H9Cl has many peaks, including a methyl group triplet at d1.0 and a methyl group doublet after. It's in the same family as the -CH party. Due to the chlorine atom, this doublet occurs at downfield at 1.5. As a result, the compound's composition is sec-butyl chloride.

Which of the following must be overcome by a rocket's thrust?

Answers

Answer:

the payloads weight

Explanation:

a p e x on the ground stream

Answer:

The payload's weight

Explanation:

i just took the test on a pex :)

What are the benefits of Fluoride?

Answers

Answer:

The benefits of Fluoride are rebuild (remineralize) weakened tooth enamel.slow down the loss of minerals from tooth enamel.reverse early signs of tooth decay.prevent the growth of harmful oral bacteria

Answer:

Fluoride is often called nature's cavity fighter and for good reason. Fluoride, a naturally-occurring mineral, helps prevent cavities in children and adults by making the outer surface of your teeth (enamel) more resistant to the acid attacks that cause tooth decay.

How many moles of hydrogen

are in 3.06 x 10^-3 g of glycine C2H5NO2

Answers

Answer:

2.04x10⁻⁴ mol

Explanation:

First we convert 3.06x10⁻³ grams of glycine into moles of glycine, using its molar mass:

3.06x10⁻³ g ÷ 75 g/mol = 4.08x10⁻⁵ mol C₂H₅NO₂

In order to calculate the number of hydrogen moles, we multiply the number of glycine moles by 5, as there are 5 hydrogen moles per glycine mol:

4.08x10⁻⁵ mol C₂H₅NO₂ * 5 = 2.04x10⁻⁴ mol H

What is true about renewable resources?

They are rare on Earth.
They can be replenished fast.
They can be replenished over millions of years.
They are very abundant on Earth.

Answers

They can be replenished fast.

Which nitrogenous base is NOT found in DNA? *
A. cytosine
B. guanine
C. uracil
D. adenine

Answers

Answer:

c. uracil

Explanation:

uracil is not found in DNA. the missing base would be thymine

how many molecules of sodium chloride are in 2.5 moles??

Answers

Answer:

1.5x1024

Explanation:

A piece of unknown solid substance weighs 437.2 g, and requires 8460 J to increase its temperature from 19.3 °C to 68.9 °C.What is the specific heat of the substance?

Answers

Answer:

0.3832

Explanation:

Givens

m = 437.2 grams

c = ?

delta t = 69.8 - 19.3

H = 8460 J

Formula

H = m*c*Δt

Solution

8460 = 437.2 * c * (69.8 - 19.3)

8460 = 437.2 * c * 50.5

8460 = 22078.6 * c

c = 8460 / 22078,6

c = .3832 J / (oC * gr)

Atoms with 5 or more valence electrons tend to form __________________ ions, called _________.

Answers

Answer:

positively-charged  cations

Explanation:

hope this helps! :)

A 90-m3 basement in a residence is found to be contaminated with radon coming from the ground through the floor drains. The concentration of radon in the room is 1.5 Bq/L under steady-state conditions. The room behaves as a CSTR and the decay of radon is a first-order reaction with a decay rate constant of 2.09 3 1026 s21 . If the source of radon is closed off and the room is vented with radon-free air at a rate of 0.14 m3 /s, how long will it take to lower the radon concentration to an acceptable level of 0.15 Bq/L

Answers

Answer:

25 minutes

Explanation:

V = Volume = [tex]90\ \text{m}^3[/tex]

[tex]C_0[/tex] = Radon concentration under steady state = 1.5 Bq/L

k = Radon decay rate = [tex]2.09\times 10^{-6}\ \text{s}^{-1}[/tex]

[tex]Q[/tex] = Venting rate = [tex]0.14\ \text{m}^3/\text{s}[/tex]

[tex]C_f[/tex] = Final concentration of radon = 0.15 Bq/L

Theoretical detention time is given by

[tex]\theta=\dfrac{V}{Q}\\\Rightarrow \theta=\dfrac{90}{0.14}\\\Rightarrow \theta=642.86\ \text{s}[/tex]

We have the relation

[tex]C_f=C_0e^{-(\dfrac{1}{\theta}+k)t}\\\Rightarrow t=\dfrac{\ln\dfrac{C_f}{C_0}}{-(\dfrac{1}{\theta}+k)}\\\Rightarrow t=\dfrac{\ln\dfrac{0.15}{1.5}}{-(\dfrac{1}{642.86}+2.09\times 10^{-6})}\\\Rightarrow t=1478.25\ \text{s}=\dfrac{1478.25}{60}=24.63\approx 25\text{minutes}[/tex]

The time taken to reach the acceptable level of concentration is 25 minutes.

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